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词条 Self-discharge
释义

  1. Typical self-discharge by battery type

  2. References

  3. Further reading

  4. External links

{{original research|date=March 2019}}

Self-discharge is a phenomenon in batteries in which internal chemical reactions reduce the stored charge of the battery without any connection between the electrodes. Self-discharge decreases the shelf life of batteries and causes them to initially have less than a full charge when actually put to use.

How fast self-discharge in a battery occurs is dependent on the type of battery, state of charge, charging current, ambient temperature and other factors. Primary batteries aren't designed for recharging between manufacturing and use, thus have battery chemistry that has to have a much lower self-discharge rate than older types of Secondary cells, but they have lost that advantage with the development of rechargeable Secondary Cells with very low self discharge rates like Low Self Discharge NiMH cells.

Self-discharge is a chemical reaction, just as closed-circuit discharge is, and tends to occur more quickly at higher temperatures. Storing batteries at lower temperatures thus reduces the rate of self-discharge and preserves the initial energy stored in the battery. Self-discharge is also thought to be reduced as a passivation layer develops on the electrodes over time.

Typical self-discharge by battery type

Battery chemistry Rechargeable Typical self-discharge or shelf life
Lithium metal No 10 years shelf life
Alkaline No 5 years shelf life
Zinc–carbon No 2–3 years shelf life
Lithium-ion Yes 2–3% per month; ca. 4% p.m.[1]
Lithium-polymer Yes ~5% per month[2]
Low self-discharge NiMH Yes As low as 0.25% per month[3]
Lead–acid Yes 4–6% per month
Nickel–cadmium Yes 15–20% per month
Nickel–metal hydride (NiMH) Yes 30% per month

References

1. ^Umweltbundesamt: [https://www.umweltbundesamt.de/sites/default/files/medien/publikation/long/4414.pdf "BATTERIEN UND AKKUS"] (3,65 MB PDF), October 2012; visited 2018-02-14
2. ^Wikipedia: Lithium polymer battery; visted 2019-02-10
3. ^Panasonic:  

Further reading

  • Wu and White, "Self-Discharge Model of a Nickel-Hydrogen Cell." Journal of the Electrochemical Society, 147 (3) 901-909 (2000)

External links

  • [https://www.amperis.com/en/products/misc/battery-dischargers/ Battery dischargers] Description and treatment of sulphated batteries
{{Use dmy dates|date=July 2011}}

3 : Battery (electricity)|Battery charging|Rechargeable batteries

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