| 词条 | Silver chlorate |
| 释义 |
| Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 464390935 | Name = Silver(I) chlorate | ImageFile = Silver-chlorate-3D-vdW.png | ImageName = Silver(I) chlorate | OtherNames = chloric acid silver salt |Section1={{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 7991255 | PubChem = 9815505 | InChI = 1/Ag.ClHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1 | InChIKey = SDLBJIZEEMKQKY-REWHXWOFAI | SMILES = [Ag+].[O-]Cl(=O)=O | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/Ag.ClHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = SDLBJIZEEMKQKY-UHFFFAOYSA-M | CASNo_Ref = {{cascite|changed|??}} | CASNo = 7783-92-8 | EINECS = 232-034-9 |Section2={{Chembox Properties | Formula = AgClO3 | MolarMass = 191.319 g/mol | Appearance = white crystals | Density = 4.443 g/cm3, solid | MeltingPtC = 230 | BoilingPtC = 250 | BoilingPt_notes = (decomposes) | Solubility = slightly soluble | SolubleOther = soluble in water and ethanol alcohol }} |Section3={{Chembox Structure | CrystalStruct = tetragonal |Section7={{Chembox Hazards | NFPA-H = 2 | NFPA-F = 0 | NFPA-R = 1 | NFPA-S = OX }} }} Silver chlorate (AgClO3) forms white, tetragonal crystals.[1][2] Like all chlorates, it is water-soluble and an oxidizing agent. As a simple metal salt, it is a common chemical in basic inorganic chemistry experiments. It is light-sensitive, so it must be stored in tightly closed dark-coloured containers. The substance exhibits blasting properties, therefore it is sometimes used as a primary explosive. Silver(I) means silver is in its normal +1 oxidation state. ProductionSilver chlorate is produced by the reaction of silver nitrate with sodium chlorate to produce both silver chlorate and sodium nitrate. Alternatively, it may be produced by the transmission of chlorine through a suspension of silver oxide. See also
References1. ^{{cite journal|last1=Náray-Szabó|first1=St. v.|last2=Pócza|first2=J.|title=Die Struktur des Silberchlorats AgClO3|journal=Zeitschrift für Kristallographie - Crystalline Materials|date=January 1942|volume=104|issue=1|doi=10.1524/zkri.1942.104.1.28|language=German}} {{Silver compounds}}{{inorganic-compound-stub}}2. ^{{cite journal|last1=Deshpande|first1=Vilas|last2=Suryanarayana|first2=S V|last3=Frantz|first3=C|title=Tetragonal to cubic phase transition in silver chlorate|journal=Bulletin of Materials Science|date=December 1982|volume=4|issue=5|pages=563–568|doi=10.1007/BF02824963}} 3 : Chlorates|Silver compounds|Oxidizing agents |
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