| 词条 | Sodium thioantimoniate |
| 释义 |
| Watchedfields = changed | verifiedrevid = 419367898 | Name = Sodium thioantimoniate | ImageFile = Na3SbS4.jpg | ImageSize = 280px | ImageName = Sodium thioantimoniate | IUPACName = Sodium tetrathioantimonate(V) |Section1 = {{Chembox Identifiers |Section2 = {{Chembox Properties | Formula = Na3SbS4·9H2O | Appearance = Yellow crystals | Density = 1.806 g/cm3, solid | MeltingPtC = 87 | MeltingPt_notes = | BoilingPt = }} |Section8={{Chembox Related | OtherCations = Potassium thioantimoniate | OtherCompounds = Antimony(III) sulfide}} }} Sodium thioantimoniate is an inorganic compound with the formula Na3SbS4. The nonahydrate of this material is known as Schlippe's salt, named after K. F. Schlippe (1799–1867), These compounds are examples of sulfosalts. They were once of interest as species generated in qualitative inorganic analysis. StructureThis hydrated salt consists of the tetrahedral SbS43− anion (rSb-S = 2.33 Å) and sodium cations, which are hydrated.[1][2] Related salts are known for different cations including ammonium and potassium. The anhydrous salt is polymer with tetrahedral Na and Sb sites.[3] PreparationSodium thioantimoniate is prepared by the reaction of antimony trisulfide, elemental sulfur, and aqueous sulfide source. 3 Na2S + 2 S + Sb2S3 + 9 H2O → 2 Na3SbS4·9 H2O The sulfide can be generated indirectly by the thermal reaction of elemental sulfur with sodium hydroxide or even charcoal: Sb2S3 + 8 NaOH + 6 S → 2 Na3SbS4 + Na2SO4 + 4 H2O In the latter route, a mixture of sodium sulfate (16 parts) is reduced by fusion with charcoal (4-5 parts) in the presence of antimony sulfide (13 parts). The melt is extracted into water which is treated with sulfur (4 parts). Upon evaporation of the solution, the salt crystallizes as large tetrahedra, which are easily soluble in water. The anhydrous salt melts easily on heating, and in the hydrated condition, on exposure to moist air becomes coated with a red film. The required antimony(III) sulfide is prepared in the usual way by treatment of virtually any Sb(III) compound with sulfide sources: 2 SbCl3 + 3 H2S → Sb2S3 + 6 HCl ReactionsThe hydrate dissolves in water to give the tetrahydral SbS43− ion. The salt gives "quinsulfide antimony," upon acidification: 2 Na3SbS4 + 6 HCl → Sb2S5 + 6 NaCl + 3 H2S Related compounds
Notes1. ^Krebs, B., "Thio- and Seleno Compounds of Main Group Elements - New Inorganic Oligomers and Polymers", Angewandte Chemie, 1983, volume 95, pages 113-34. 2. ^K. Mereiter, A. Preisinger and H. Guth "Hydrogen bonds in Schlippe's salt: refinement of the crystal structures of Na3SbS4.9H2O by X-ray diffraction and Na3SbS4.9D2O by neutron diffraction at room temperature" Acta Crystallographica 1979, vol. B35, 19-25. {{doi|10.1107/S0567740879002442}}. 3. ^H. A. Graf, H. Schäfer "Zur Strukturchemie der Alkalisalze der Tetrathiosäuren der Elemente der 5. Hauptgruppe (pages 67–80) Zeitschrift für Anorganische und Allgemeine Chemie 1976, vol. 425, p67-p80. {{DOI|10.1002/zaac.19764250109}} References
3 : Antimony compounds|Sulfides|Sodium compounds |
| 随便看 |
|
开放百科全书收录14589846条英语、德语、日语等多语种百科知识，基本涵盖了大多数领域的百科知识，是一部内容自由、开放的电子版国际百科全书。