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词条 Sodium trimetaphosphate
释义

  1. References

{{Chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 451978784
| ImageFile = Sodium trimetaphosphate.png
| ImageSize = 180px
| Reference = [1]
| IUPACName =
| OtherNames = Sodium trimetaphosphate
|Section1={{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 7785-84-4
| PubChem = 24579
| EINECS = 232-088-3
| InChI = 1S/3Na.H3O9P3/c;;;1-10(2)7-11(3,4)9-12(5,6)8-10/h;;;(H,1,2)(H,3,4)(H,5,6)/q3*+1;/p-3
| SMILES = O=P(OP(O1)([O-])=O)([O-])OP1([O-])=O.[Na+].[Na+].[Na+]}}
|Section2={{Chembox Properties
| Formula = Na3P3O9
| MolarMass = 305.885 g/mol
| Appearance = colorless or white crystals
| Density = 2.49 g/cm3 (anhydrous)
1.786 g/cm3 (hexahydrate)
| MeltingPtC = 53
| MeltingPt_notes = (hexahydrate, decomposes to anyhdrous)
| BoilingPt =
| Solubility = 22 g/100 mL
| SolubleOther = insoluble in alcohol
| RefractIndex = 1.433 (hexahydrate)
}}
|Section3={{Chembox Structure
| CrystalStruct = triclinic (hexahydrate)
}}
|Section5={{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt =
|Section6={{Chembox Thermochemistry
| DeltaHf =
| DeltaHc =
| Entropy =
| HeatCapacity =
}}

Sodium trimetaphosphate (also STMP), with formula Na3P3O9, is a metaphosphate of sodium. It has the empirical formula NaPO3. It is the sodium salt of trimetaphosphoric acid. It is a colourless solid that finds specialised applications in food and construction industries. STMP is prepared by heating sodium polyphosphate at a few hundred degrees.

[2]

Although drawn with a particular resonance structure, the trianion has D3d symmetry.

References

1. ^{{cite book | last = Lide | first = David R. | year = 1998 | title = Handbook of Chemistry and Physics | edition = 87 | volume = | location = Boca Raton, Florida | publisher = CRC Press | isbn = 0-8493-0594-2 | pages = 4–86}}
2. ^{{cite book|author1=Klaus Schrödter|author2=Gerhard Bettermann|author3=Thomas Staffel|author4=Friedrich Wahl|author5=Thomas Klein|author6=Thomas Hofmann|title=Phosphoric Acid and Phosphates|series=Ullmann’s Encyclopedia of Industrial Chemistry|year=2008|publisher=Wiley-VCH|place=Weinheim|doi=10.1002/14356007.a19_465.pub3}}
{{DEFAULTSORT:Sodium Trimetaphosphate}}{{inorganic-compound-stub}}

3 : Food additives|Sodium compounds|Phosphates

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