| 词条 | Stollé synthesis |
| 释义 |
The Stollé synthesis is a series of chemical reactions that produce oxindoles from anilines and α-haloacid chlorides (or oxalyl chloride).[1][2][3][4] The first step is an amide coupling, while the second step is a Friedel–Crafts reaction.[5][6] An improved procedure has been developed.[7][8] See also
References1. ^{{cite journal|last = Stollé|first = R.|journal = Ber.|year = 1913|volume = 46|issue = 3|pages = 3915-3916|doi = 10.1002/cber.191304603186|title = Über eine neue Methode zur Darstellung N-substituierter Isatine. (Vorläufige Mitteilung)|language = German}} {{DEFAULTSORT:Stolle synthesis}}2. ^{{cite journal|last=Stollé|first=R.|journal=Ber.|year=1914|volume=47|issue=2|pages= 2120-2122|doi=10.1002/cber.191404702112|title=Über Phenyl-oxindol|language=German}} 3. ^{{cite journal|last1=Stollé|first1=R.|first2=R.|last2=Bergdoll|first3=M.|last3=Luther|first4=A.|last4=Auerhahn|first5=W.|last5=Wacker|journal=J. Prakt. Chem.|year=1922|volume=105|issue=1|pages=137-148|doi=10.1002/prac.19221050111|title=Über N-substituierte Oxindole und Isatine|language=German}} 4. ^{{cite journal|last1=Stollé|first1=R.|first2=R.|last2=Bergdoll|first3=M.|last3=Luther|journal=J. Prakt. Chem.|first4=A.|last4=Auerhahn|first5=W.|last5=Wacker|year=1930|volume=128|issue=1|pages=1-43|title=Über N-substituierte Oxindole und Isatine|language=German|doi=10.1002/prac.19301280101}} 5. ^{{cite journal|last=Sumpter|first=Ward C.|journal=Chem. Rev.|year=1944|volume=34|pages=393-434|doi=10.1021/cr60109a003|title=The Chemistry of Isatin|issue=3}} 6. ^{{cite journal|last=Sumpter|first=Ward C.|journal=Chem. Rev.|year=1945|volume=37|pages=443–479|doi=10.1021/cr60118a003|title=The Chemistry of Oxindole|issue=3}} 7. ^{{cite journal|first1=Percy L.|last1=Julian|first2=Josef|last2=Pikl|journal=J. Am. Chem. Soc.|year=1935|volume=57|pages= 563-566|doi=10.1021/ja01306a053|title=Studies in the Indole Series. IV. The Synthesis of d,l-Eserethole|issue=3}} 8. ^{{OrgSynth | last1 = Rutenberg | first1 = M. W. |last2 = Horning | first2 = E. C. | collvol = 4 | collvolpages = 620 | year = 1950 | prep = cv4p0620 | title = 1-Methyl-3-ethyloxindole (Oxindole, 3-ethyl-1-methyl) | volume = 30 | pages = 62 | doi = 10.15227/orgsyn.030.0062}} 3 : Carbon-carbon bond forming reactions|Heterocycle forming reactions|Name reactions |
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