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词条 Tert-Butyl acetate
释义

  1. See also

  2. References

  3. External links

{{DISPLAYTITLE:tert-Butyl acetate}}{{chembox
| Watchedfields = changed
| verifiedrevid = 470602783
| Name = tert-Butyl acetate
| ImageFile = T-butyl acetate.png
| ImageSize = 150px
| ImageAlt = Skeletal formula of tert-butyl acetate
| ImageFile1 = Tert-Butyl acetate 3D ball.png
| ImageSize1 = 190px
| ImageAlt1 = Ball-and-stick model of the tert-butyl acetate molecule
| PIN = tert-Butyl acetate
| OtherNames = {{ubl
| Acetic acid tert-butyl ester
| t-Butyl acetate
|Section1={{Chembox Identifiers
| SMILES = O=C(OC(C)(C)C)C
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 10446
| PubChem = 10908
| InChI = 1/C6H12O2/c1-5(7)8-6(2,3)4/h1-4H3
| InChIKey = WMOVHXAZOJBABW-UHFFFAOYAQ
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/C6H12O2/c1-5(7)8-6(2,3)4/h1-4H3
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = WMOVHXAZOJBABW-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 540-88-5
|Section2={{Chembox Properties
| C=6 | H=12 | O=2
| Appearance = Colorless liquid
| Odor = Fruity
| Density = 0.8593{{nbsp}}g/cm3[1]
| Solubility = 0.8{{nbsp}}wt% at 22{{nbsp}}°C
| SolubleOther = Miscible[1]
| Solvent = ether and ethanol
| MeltingPt =
| BoilingPtC = 97.8
| BoilingPt_ref = [1]
| Viscosity =
|Section3={{Chembox Structure
| MolShape =
| Dipole =
|Section7={{Chembox Hazards
| ExternalSDS =
| MainHazards = Flammable
| PEL = TWA 200{{nbsp}}ppm (950{{nbsp}}mg/m3)[2]
| FlashPtF = 72
| FlashPt_ref = [2]
| ExploLimits = From 1.5% to unknown[2]
| IDLH = 1500{{nbsp}}ppm[2]
| REL = TWA 200{{nbsp}}ppm (950{{nbsp}}mg/m3)[2]
}}

tert-Butyl acetate, t-butyl acetate or TBAc is a colorless flammable liquid with a camphor- or blueberry-like smell. It is used as a solvent in the production of lacquers, enamels, inks, adhesives, thinners and industrial cleaners. It has recently gained EPA volatile organic compound (VOC) exempt status[3].

It is manufactured from acetic acid and isobutylene.[1]

Butyl acetate has four isomers: tert-butyl acetate, n-butyl acetate, isobutyl acetate, and sec-butyl acetate.

See also

  • tert-Butyl formate
  • PCBTF VOC Exempt

References

1. ^{{cite work | work = Merck Index | edition = 11th | title = tert-Butyl acetate | page = 236}}
2. ^{{PGCH|0074}}
3. ^{{Cite web|url=https://www.paint.org/voc-exempt/|title=Update: U.S. EPA Exempt Volatile Organic Compounds|date=2018-01-30|website=American Coatings Association|language=en-US|access-date=2019-03-20}}

External links

  • ChemExpr.com
  • [https://www.cdc.gov/niosh/npg/npgd0074.html CDC - NIOSH Pocket Guide to Chemical Hazards]
{{DEFAULTSORT:Butyl acetate, tert-}}

3 : Ester solvents|Acetate esters|Tert-butyl compounds

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