“Tetraazidomethane”的意思、由来-开放百科全书

词条

Tetraazidomethane

释义

Synthesis
Uses
Reactions
References

{{Not to be confused with|Cranial nerve 12}}{{chembox
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| verifiedrevid = 470603291
| Name = Tetraazidomethane
| ImageFileL1 = tetraazidomethane.png
| ImageSizeL1 = 120px
| ImageNameL1 = Tetraazidomethane
| ImageFileR1 = tetraazidomethane 3D.png
| ImageSizeR1 = 120px
| ImageNameR1 = Tetraazidomethane
| IUPACName = Tetraazidomethane
| Section1 = {{Chembox Identifiers
| PubChem = 16059578
| InChI = 1/CN12/c2-10-6-1(7-11-3,8-12-4)9-13-5
| InChIKey = PGNZIEKVQCKOBT-UHFFFAOYAX
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/CN12/c2-10-6-1(7-11-3,8-12-4)9-13-5
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = PGNZIEKVQCKOBT-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|changed|??}}
| CASNo = 869384-16-7
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID=17219283
| SMILES = [N-]=[N+]=N\\C(\=[N+]=[N-])(\=[N+]=[N-])\=[N+]=[N-]
}}
| Section2 = {{Chembox Properties
| Formula = CN₁₂
| MolarMass = 180.09 g/mol
| Density =
| BoilingPt = ~165 °C (estimate)
}}

Tetraazidomethane is a colorless, highly explosive liquid. Its chemical structure consists of a carbon atom substituted with four azide functional groups.

Synthesis

It was first prepared by Klaus Banert in 2006 by reaction of trichloroacetonitrile with sodium azide.^[1]

Uses

As with other polyazides, tetraazidomethane has interest as a high-energy-density material with potential uses in explosives, propellants, or fireworks.^[2] Silicon tetraazide is also a known compound.

Reactions

Banert has reported that tetraazidomethane participates in a number of surprising reactions including hydrolysis, cycloaddition reactions with alkenes and alkynes, and reaction with phosphines to form phosphazenes.^[1]

References

1. ^¹"The Exciting Chemistry of Tetraazidomethane", Klaus Banert, Young-Hyuk Joo, Tobias Ruffer, Bernhard Walfort, and Heinrich Lang, Angew. Chem. Int. Ed. 2007, 46, 1168–1171. {{DOI|10.1002/anie.200603960}}
2. ^"Tetraazidomethane: Chemistry with a Bang", Chemical & Engineering News, Dec. 18, 2006, 46.

2 : Azides|Explosive chemicals

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