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词条 Tributyltin oxide
释义

  1. References

  2. External links

{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 470613357
| Name =
| ImageFile = Tributyltin oxide structure.svg
| ImageSize =
| ImageFile1 = Tributyltin-oxide-3D-vdW.png
| ImageSize1 =
| IUPACName = hexabutyldistannoxane
| OtherNames = bis(tributyltin) oxide, bis(tri-n-butyltin)oxide, AW 75-D, Bio-Met TBTO, Biomet, Biomet 75, BTO, Butinox, C-SN-9
| SystematicName =
| Section1 = {{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 10218152
| InChI = 1/6C4H9.O.2Sn/c6*1-3-4-2;;;/h6*1,3-4H2,2H3;;;/rC24H54OSn2/c1-7-13-19-26(20-14-8-2,21-15-9-3)25-27(22-16-10-4,23-17-11-5)24-18-12-6/h7-24H2,1-6H3
| InChIKey = APQHKWPGGHMYKJ-XAMPVVILAF
| ChEMBL_Ref = {{ebicite|correct|EBI}}
| ChEMBL = 511667
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/6C4H9.O.2Sn/c6*1-3-4-2;;;/h6*1,3-4H2,2H3;;;
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = APQHKWPGGHMYKJ-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 56-35-9
| PubChem = 16682746
| KEGG_Ref = {{keggcite|changed|kegg}}
| KEGG = C18149
| SMILES = CCCC[Sn](CCCC)(CCCC)O[Sn](CCCC)(CCCC)CCCC
}}
| Section2 = {{Chembox Properties
| Formula = C24H54OSn2
| MolarMass = 596.112
| Appearance =
| Density =
| MeltingPtC = -45
| BoilingPtC = 180
| BoilingPt_notes = at 2 mm Hg
| Solubility = 0.002 g/100 mL
| LogP = 5.02[1]
| Section3 = {{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt =
| RPhrases = {{R21}} {{R25}} {{R36/38}} {{R48/23/25}} {{R50/53}}
| SPhrases = {{S36/37/39}} {{S45}} {{S60}} {{S61}}
| Section4 =
| Section5 =
| Section6 =
}}

Tributyltin oxide (TBTO) is an organotin compound chiefly used as a biocide (fungicide and molluscicide), especially a wood preservative. Its chemical formula is [(C4H9)3Sn]2O. It has the form of a colorless to pale yellow liquid that is only slightly soluble in water (20 ppm) but highly soluble in organic solvents. It is a potent skin irritant.

Tributyltin compounds had been used as marine anti-biofouling agents. Concerns over toxicity of these compounds have led to a worldwide ban by the International Maritime Organization.[2] It is now considered a severe marine pollutant and a Substance of Very High Concern by the EU.[3]

References

1. ^{{Cite web|url=https://www.chemsrc.com/en/cas/56-35-9_743423.html|title=Tributyltin oxide_msds}}
2. ^{{cite news | url=http://www.imo.org/OurWork/Environment/Anti-foulingSystems/Documents/FOULING2003.pdf | title=Focus on IMO - Anti-fouling systems | publisher=International Maritime Organisation}}
3. ^Organotin Chemistry, Second Edition. Alwyn G. Davies, 2004, Wiley-VCH Verlag GmbH & Co. KGaA. {{ISBN|3-527-31023-1}}

External links

  • [https://web.archive.org/web/20060411081425/http://www.npi.gov.au/database/substance-info/profiles/66.html National Pollutant Inventory Fact Sheet for organotins]
  • {{PPDB|2585}}

5 : PBT substances|Fungicides|Molluscicides|Organotin compounds|Oxides

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