词条 | Von Braun amide degradation |
释义 |
The von Braun amide degradation is the chemical reaction of a monosubstituted amide with phosphorus pentachloride or thionyl chloride to give a nitrile and an organohalide.[1] It is named after Julius Jacob von Braun, who first reported the reaction.[2][3] See also
References1. ^{{cite journal | title = Ueber die Spaltung des Benzenylmethylimidchlorids | author = Hans von Pechmann | journal = Berichte der deutschen chemischen Gesellschaft | volume = 33 | issue = 1 | pages = 611–612 | year = 1900 | url = http://gallica.bnf.fr/ark:/12148/bpt6k907551/f616.table | doi = 10.1002/cber.19000330199}} 2. ^{{cite journal | title = Ueber 1.5-Dibrompentan | author = von Braun, J. | journal = Berichte der deutschen chemischen Gesellschaft | volume = 37 | issue = 3 | pages = 3210–3213 | year = 1904 | url = | doi = 10.1002/cber.190403703118 }} 3. ^{{cite journal | title = Mechanism of the von Braun amide degradations with carbonyl bromide or phosphorus pentabromide | author = B. A. Phillips, G. Fodor, J. Gal, F. Letourneau and J. J. Ryan | journal = Tetrahedron | volume = 29 | issue = 21 | pages = 3309–3327 | year = 1973 | url = | doi = 10.1016/S0040-4020(01)93483-0}} 3 : Elimination reactions|Degradation reactions|Name reactions |
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