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词条 Yttrium(III) fluoride
释义

  1. Synthesis

  2. Occurrence and uses

  3. Hazards

  4. References

{{chembox
| verifiedrevid = 470635281
| Name = Yttrium(III) fluoride
| ImageFile = Kristallstruktur Yttrium(III)-fluorid.png
| ImageName = Yttrium(III) fluoride
| OtherNames = yttrium trifluoride
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 75502
| InChI = 1/3FH.Y/h3*1H;/q;;;+3/p-3
| InChIKey = RBORBHYCVONNJH-DFZHHIFOAP
| SMILES = F[Y](F)F
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/3FH.Y/h3*1H;/q;;;+3/p-3
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = RBORBHYCVONNJH-UHFFFAOYSA-K
| CASNo = 13709-49-4
| CASNo_Ref = {{cascite|correct|CAS}}
| PubChem = 83679
| EC_number = 237-257-5
|Section2={{Chembox Properties
| Formula = YF3
| MolarMass = 145.90 g mol−1
| Appearance = white powder
| Density = 4.01 g cm−3
| Solubility = insoluble
| Solvent = acid
| SolubleOther = soluble
| MeltingPtC = 1387
| BoilingPtC = 2230
| RefractIndex = 1.51 (500 nm)
|Section3={{Chembox Structure
| CrystalStruct = Orthorhombic, oP16, SpaceGroup = Pnma, No. 62
}}
|Section7={{Chembox Hazards
| ExternalSDS =
| NFPA-H =
| NFPA-R =
| NFPA-F =
| FlashPt = Non-flammable
| GHSPictograms = {{GHS07}}
| GHSSignalWord = Warning
| HPhrases = {{H-phrases|302|312|315|319|332|335}}
| PPhrases = {{P-phrases|261|264|270|271|280|301+312|302+352|304+312|304+340|305+351+338|312|321|322|330|332+313|337+313|362|363|403+233|405|501}}
|Section8={{Chembox Related
| OtherAnions = Yttrium(III) chloride
Yttrium(III) bromide
Yttrium(III) iodide
| OtherCations = Scandium(III) fluoride
Lanthanum(III) fluoride
}}

Yttrium(III) fluoride is an inorganic chemical compound with the chemical formula YF3. It is not known naturally in 'pure' form. The fluoride minerals containing essential yttrium include tveitite-(Y) (Y,Na)6Ca6Ca6F42 and gagarinite-(Y) NaCaY(F,Cl)6. Sometimes mineral fluorite contains admixtures of yttrium.

Synthesis

YF3 can be produced by reacting fluorine with yttria or yttrium hydroxide with hydrofluoric acid.

Y(OH)3 + 3HF → YF3 + 3H2O

Occurrence and uses

It occurs as the mineral waimirite-(Y).[1]

Yttrium(III) fluoride can be used for the production of metallic yttrium, thin films, glasses and ceramics.

Hazards

Conditions/substances to avoid are: acids, active metals and moisture.

References

{{Unreferenced|date =September 2007}}
1. ^https://www.mindat.org/min-46049.html
{{Yttrium compounds}}{{fluorine compounds}}{{inorganic-compound-stub}}

4 : Fluorides|Metal halides|Yttrium compounds|Inorganic compound stubs

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