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词条 Zero field NMR
释义

  1. See also

  2. References

  3. Further reading

  4. External links

Zero field NMR is the acquisition of nuclear magnetic resonance spectra in an environment carefully screened from magnetic fields (Including from the Earth's field). It is useful for studying chemicals with magnetically active nuclei (spins 1/2 and greater), and for studying molecular dynamics.

The development of very sensitive magnetic sensors such as SQUID, GMR, and atomic magnetometers in the 2000s has made it possible to detect NMR signals directly in zero-field environments. Previous zero-field NMR experiments relied on indirect detection where the sample had to be shuttled from the shielded zero-field environment into a high magnetic field for detection with a conventional inductive pick-up coil.

One successful implementation was using atomic magnetometers at zero magnetic field working with rubidium vapor cells to detect zero-field NMR.[1][2]

It is sometimes but inaccurately referred to as nuclear quadrupole resonance (NQR).[3]

See also

  • Earth's field NMR
  • Low field NMR

References

1. ^{{cite journal|last1=Sheng|first1=D.|last2=Li|first2=S.|last3=Dural|first3=N.|last4=Romalis|first4=M.|title=Subfemtotesla Scalar Atomic Magnetometry Using Multipass Cells|journal=Physical Review Letters|date=18 April 2013|volume=110|issue=16|doi=10.1103/PhysRevLett.110.160802|url=http://link.aps.org/doi/10.1103/PhysRevLett.110.160802|arxiv = 1208.1099 |bibcode = 2013PhRvL.110p0802S|pmid=23679590|page=160802}}
2. ^{{cite journal |url= http://physicsworld.com/cws/article/news/2013/apr/24/atomic-magnetometer-is-most-sensitive-yet |date= April 24, 2013 |title= Atomic magnetometer is most sensitive yet |first= Tushna |last= Commissariat |journal= Physics World }}
3. ^{{US patent|6919838}}

Further reading

  • M. P. Ledbetter, C. Crawford, A. Pines, D. Wemmer, S. Knappe, J. Kitching, D. Budker "Optical detection of NMR J-spectra at zero magnetic field" J. Magn. Reson. (2009), 199, 25-29.
  • T. Theis, P. Ganssle, G. Kervern, S. Knappe, J. Kitching, M. P. Ledbetter, D. Budker and A. Pines; “[https://pines.berkeley.edu/sites/default/files/publications/parahydrogren-enhanced_zero-field_nuclear_magnetic_resonance.pdf Parahydrogen-enhanced zero-field nuclear magnetic resonance]” Nature Physics (2011), 7, 571–575.

External links

  • https://pines.berkeley.edu/research/ultra-low-field-zero-field-nmr
  • https://pines.berkeley.edu/publications/chemical-analysis-using-j-coupling-multiplets-zero-field-nmr-0
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1 : Nuclear magnetic resonance

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