| 词条 | 1-Phenylethylamine |
| 释义 |
| Watchedfields = changed | verifiedrevid = 477188998 | Name = 1-Phenylethylamine | Reference = [1] | ImageFile = 1-phenethylamine.png | ImageName = Chemical structure of 1-Phenylethylamine | PIN = 1-Phenylethan-1-amine | OtherNames = (±)-1-Phenylethylamine (±)-α-Methylbenzylamine | Section1 = {{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChEBI_Ref = {{ebicite|correct|EBI}} | ChEBI = 670 | ChemSpiderID = 7130 | KEGG_Ref = {{keggcite|correct|kegg}} | KEGG = C02455 | InChI = 1/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3 | InChIKey = RQEUFEKYXDPUSK-UHFFFAOYAS | SMILES1 = CC(c1ccccc1)N | ChEMBL_Ref = {{ebicite|correct|EBI}} | ChEMBL = 278059 | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = RQEUFEKYXDPUSK-UHFFFAOYSA-N | CASNo_Ref = {{cascite|correct|CAS}} | CASNo = 618-36-0 | SMILES = NC(c1ccccc1)C }} | Section2 = {{Chembox Properties | C=8|H=11|N=1 | Density = 0.94 g/mL | MeltingPt = -65 C{{citation needed|date=November 2015}} | BoilingPtC = 187 | Section7 = {{Chembox Hazards | MainHazards = Corrosive | Section8 = {{Chembox Related | OtherFunction = (R)-(+)- (CAS [3886-69-9]) (S)-(–)- (CAS [2627-86-3]) | OtherFunction_label = stereoisomers }} 1-Phenylethylamine is the organic compound with the formula C6H5CH(NH2)CH3. Classified as a monoamine, this colorless liquid is often used in chiral resolutions. Like benzylamine, it is highly basic and forms stable ammonium salts and imines. This compound may be prepared by the reductive amination of acetophenone under various standard conditions for this type of reaction. One major route for this chemical uses the Mignonac reaction, a one-pot protocol using hydrogen gas as the reducing agent:[2] The Leuckart reaction, using ammonium formate, is another method for this transformation.[3][4] See also
References1. ^[https://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=7408 1-Phenylethylamine - PubChem Public Chemical Database] {{Phenethylamines}}{{DEFAULTSORT:Phenethylamine, 1-}}2. ^{{OrgSynth | title = α-Phenylethylamine | author = John C. Robinson, Jr. and H. R. Snyder | collvol = 3 | collvolpages = 717 | year = 1955 | prep = cv3p0717}} 3. ^{{cite book|last1= Mann |first1= F. G. |last2= Saunders |first2= B. C.|title=Practical Organic Chemistry, 4th Ed.|year=1960|publisher=Longman|location=London|isbn=9780582444072|pages=223–224|url=https://www.scribd.com/doc/46973684/Practical-Organic-Chemistry-Frederick-George-Mann}} 4. ^{{OrgSynth | title = α-Phenylethylamine | author = A. W. Ingersoll | collvol = 17 | collvolpages = 76 | year = 1937 | prep = cv2p0503}} 1 : Phenethylamines |
| 随便看 |
|
开放百科全书收录14589846条英语、德语、日语等多语种百科知识，基本涵盖了大多数领域的百科知识，是一部内容自由、开放的电子版国际百科全书。