“4-Dehydroepiandrosterone”的意思、由来-开放百科全书

词条

4-Dehydroepiandrosterone

释义

Synonyms
References

{{Chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 477221469
| ImageFile = 3beta-Hydroxyandrost-4-en-17-one.png
| ImageSize = 250
| ImageAlt = Skeletal formula of 4-dehydroepiandrosterone
| ImageFile1 = 4-Dehydroepiandrosterone 3D ball.png
| ImageAlt1 = Ball-and-stick model of the 4-dehydroepiandrosterone molecule
| ImageSize1 = 250
| IUPACName = (3S,8R,9S,10R,13S,14S)-3-hydroxy-10,13-dimethyl-1,2,3,6,7,8,9,11,12,14,15,16-dodecahydrocyclopenta[a]phenanthren-17-one
| OtherNames = Androst-4-en-3β-ol-17-one
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 8123501
| InChI = 1/C19H28O2/c1-18-9-7-13(20)11-12(18)3-4-14-15-5-6-17(21)19(15,2)10-8-16(14)18/h11,13-16,20H,3-10H2,1-2H3/t13-,14-,15-,16-,18-,19-/m0/s1
| InChIKey = VMYTXBKVYDESSJ-USOAJAOKBU
| SMILES1 = O=C4[C@]3(CC[C@@H]2[C@@]1(C(=C/[C@@H](O)CC1)\\CC[C@H]2[C@@H]3CC4)C)C
| ChEMBL_Ref = {{ebicite|correct|EBI}}
| ChEMBL = 1077603
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/C19H28O2/c1-18-9-7-13(20)11-12(18)3-4-14-15-5-6-17(21)19(15,2)10-8-16(14)18/h11,13-16,20H,3-10H2,1-2H3/t13-,14-,15-,16-,18-,19-/m0/s1
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = VMYTXBKVYDESSJ-USOAJAOKSA-N
| CASNo_Ref = {{cascite|changed|??}}
| CASNo = 571-44-8
| PubChem = 9947889
| SMILES = O=C1CC[C@@]2([H])[C@]3([H])CCC4=C[C@@H](O)CC[C@]4(C)[C@@]3([H])CC[C@@]21C
}}
|Section2={{Chembox Properties
| C=19 | H=28 | O=2
| Appearance =
| Density =
| MeltingPt =
| BoilingPt =
| Solubility = }}
|Section3={{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt = }}
}}

4-Dehydroepiandrosterone (4-DHEA) is a steroid that is an isomer of 5-dehydroepiandrosterone.

4-DHEA has been prepared by laboratory synthesis.^[1]^[2]

Synonyms

Synonyms for 4-dehydroepiandrosterone are:

3β-Hydroxy-4-androsten-17-one, 3β-hydroxyandrost-4-en-17-one, 3β-hydroxy-D4-androsten-17-one, 3β-hydroxyandrost-4-en-17-one, 3β-hydroxy-etioallocholan-4-en-17-one, and 4-androsten-3β-ol-17-one.

References

1. ^Klimstra, Paul D.; Colton, F. B. Synthesis of 3β-hydroxyestr-4-en-17-one and 3β-hydroxyandrost-4-en-17-one. Steroids (1967), 10(4), 411-24.
2. ^Ward, Margaret G.; Orr, James C.; Engel, Lewis L. A convenient synthesis of 3β-hydroxyandrost-4-en-17-one. Journal of Organic Chemistry (1965), 30(5), 1421-3.

4 : Alcohols|Androgens and anabolic steroids|Androstanes|Ketones

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