词条 | Acetone thiosemicarbazone |
释义 |
| Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 477239379 | Reference =[1] | ImageFile =Acetone thiosemicarbazone.png | ImageSize =180px | PIN = 2-(Propan-2-ylidene)hydrazine-1-carbothioamide | OtherNames = (Propan-2-ylideneamino)thiourea Acetone thiosemicarbazide Dimethyl ketone thiosemicarbazone Thiosemicarbazone acetone NSC 711 2-(1-Methylethylidene)hydrazinecarbothioamide |Section1={{Chembox Identifiers | Abbreviations = ATSC | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 2050659 | InChI = 1/C4H9N3S/c1-3(2)6-7-4(5)8/h1-2H3,(H3,5,7,8) | InChIKey = FQUDPIIGGVBZEQ-UHFFFAOYAR | SMILES1 = S=C(N)N/N=C(\\C)C | ChEMBL_Ref = {{ebicite|correct|EBI}} | ChEMBL = 500557 | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/C4H9N3S/c1-3(2)6-7-4(5)8/h1-2H3,(H3,5,7,8) | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = FQUDPIIGGVBZEQ-UHFFFAOYSA-N | CASNo_Ref = {{cascite|changed|??}} | CASNo =1752-30-3 | PubChem =2770166 | SMILES =CC(=NNC(=S)N)C | EINECS = 217-137-9 |Section2={{Chembox Properties | C=4 | H=9 | N=3 | S=1 | Appearance =White crystals | Density = | MeltingPtC = 172 to 175 | MeltingPt_notes = | BoilingPt = | Solubility = |Section3={{Chembox Hazards | ExternalSDS =MSDS | MainHazards =Toxic | EUClass =T+ | FlashPt = | NFPA-H = 4 | NFPA-F = | NFPA-R = | AutoignitionPt = | RPhrases = {{R21}} {{R25}} {{R26}} | SPhrases = {{S22}} {{S28}} {{S36/37/39}} {{S45}} }}Acetone thiosemicarbazone is a chemical compound with the molecular formula C4H9N3S. It is used in the plastics industry in the manufacture of polyvinyl chloride (PVC) to terminate the polymerization process.[2][3] It is classified as an extremely hazardous substance in the United States as defined in Section 302 of the U.S. Emergency Planning and Community Right-to-Know Act (42 U.S.C. 11002), and is subject to strict reporting requirements by facilities which produce, store, or use it in significant quantities.[4] References1. ^Acetone thiosemicarbazone, chemicalland21.com 2. ^{{US patent reference | number = 3637632 | y = 1972 | m = Jan | d = 25 | inventor = Traynor, Lee | title = Agents for shortstopping free radical polymerization of vinylidene monomers}} 3. ^Acetone thiosemicarbazone (ATSC) {{webarchive |url=https://web.archive.org/web/20120227155656/http://www.88chem.com/product-Other-Chemicals/23356/Acetone-thiosemicarbazone-ATSC-.html |date=February 27, 2012 }}, 88chem.com 4. ^{{Cite journal | publisher = Government Printing Office | title = 40 C.F.R.: Appendix A to Part 355—The List of Extremely Hazardous Substances and Their Threshold Planning Quantities | url = http://edocket.access.gpo.gov/cfr_2008/julqtr/pdf/40cfr355AppA.pdf | edition = July 1, 2008 | accessdate = October 29, 2011 | postscript=.}} 3 : Hydrazines|Thioureas|Thiosemicarbazone |
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