| 词条 | Acetyl bromide |
| 释义 |
| Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 477239903 | Reference =[1] | ImageFileL1 = Acetyl_bromide.png | ImageAltL1 = Structural formula of acetyl bromide | ImageFileR1 = Acetyl-bromide-3D-balls.png | ImageSizeR1 = 120 | ImageAltR1 = Ball-and-stick model of acetyl bromide | PIN = Acetyl bromide | OtherNames = |Section1={{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 10050 | InChI = 1/C2H3BrO/c1-2(3)4/h1H3 | InChIKey = FXXACINHVKSMDR-UHFFFAOYAZ | SMILES1 = BrC(=O)C | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/C2H3BrO/c1-2(3)4/h1H3 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = FXXACINHVKSMDR-UHFFFAOYSA-N | CASNo_Ref = {{cascite|changed|??}} | CASNo=506-96-7 | PubChem=10482 | SMILES=CC(=O)Br |Section2={{Chembox Properties | C=2|H=3|Br=1|O=1 | Appearance= | Density=1.663 g/mL | MeltingPtC = -96 | BoilingPtC = 75 to 77 | Solubility= |Section3={{Chembox Hazards | EUClass = {{Hazchem C}} | ExternalSDS = ILO MSDS | FlashPtC=110 | AutoignitionPtC = | RPhrases = {{R14}} {{R34}} | SPhrases = {{S26}} {{S36/37/39}} {{S45}} }}Acetyl bromide is an acyl bromide compound. As is expected, it may be prepared by reaction between phosphorus tribromide and acetic acid:[2] 3 CH3COOH + PBr3 → 3 CH3COBr + H3PO3 As usual for an acid halide, acetyl bromide hydrolyzes rapidly in water, forming acetic acid and hydrobromic acid. It also reacts with alcohols and amines to produce acetate esters and acetamides, respectively. References1. ^Acetyl bromide{{dead link|date=October 2016 |bot=InternetArchiveBot |fix-attempted=yes }} at Sigma-Aldrich {{organic-compound-stub}}2. ^{{cite journal | doi = 10.1021/ja01858a502 | journal = J. Am. Chem. Soc. | title = The Preparation of Acetyl Bromide | author = Theodore M. Burton and Ed. F. Degering | year = 1940 | volume = 62 | pages = 227}} 1 : Acyl bromides |
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