| 词条 | Dichloro(cycloocta-1,5-diene)platinum(II) |
| 释义 |
| verifiedrevid = 396330050 | ImageFile=Cl2Ptcod.png | ImageSize=150 | ImageFile1=Dichloro(cycloocta-1,5-diene)platinum(II)-from-xtal-3D-balls-A.png | IUPACName= | OtherNames= |Section1={{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 4642949 | InChI = 1/C8H12.2ClH.Pt/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;; | InChIKey = VVAOPCKKNIUEEU-AUZMAREFBX | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/C8H12.2ClH.Pt/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;; | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = VVAOPCKKNIUEEU-PHFPKPIQSA-L | CASNo_Ref = {{cascite|correct|CAS}} | CASNo=12080-32-9 | PubChem=5702648 | SMILES = Cl[Pt]Cl.C\\1=C\\CC/C=C\\CC/1 }} |Section2={{Chembox Properties | C=8 | H=12 | Cl=2 | Pt=1 | Appearance= | Density= | MeltingPtC=285 | BoilingPt= | Solubility= |Section3={{Chembox Hazards | EUClass = {{Hazchem Xi}} | RPhrases = {{R36/37/38}} | SPhrases = {{S26}}-{{S37/39}} | FlashPt= | AutoignitionPt = }} Dichloro(1,5-cyclooctadiene)platinum(II) (Pt(cod)Cl2) is an organometallic compound of platinum. This colourless solid is an entry point to other platinum compounds through the displacement of the cod and/or chloride ligands. It is one of several complexes of 1,5-cyclooctadiene. Dichloro(1,5-cyclooctadiene)platinum(II) is prepared by treating potassium tetrachloroplatinate with the diene:[1] K2PtCl4 + C8H12 → PtCl2C8H12 + 2 KCl According to X-ray crystallography, the complex is square planar.[2][3] See also
References1. ^{{cite journal |author1=E. Costa |author2=P. G. Pringle |author3=M. Ravetz | title = [(1,2,5,6-η)-1,5-Cyclooctadiene]Dimethyl-Platinum(II)| journal = Inorg. Synth. | year = 1997 | volume = 31 | pages = 284–286 | doi = 10.1002/9780470132623.ch49 | series = Inorganic Syntheses | isbn = 978-0-470-13262-3}} 2. ^{{cite journal|journal=Inorganica Chimica Acta|volume=65|year=1982|pages=L205-L206|title=Chemistry of Metal diene complexes: X-ray crystal structure of dichloro(1,5-cyclooctadine)platinum(II)|authors=Anil B. Goel, Sarla Goel, Don Van Der Veer|doi=10.1016/S0020-1693(00)93548-5}} 3. ^{{cite journal | title = Reexamination of the π bonding in dichloro(cycloocta-1,5-diene)platinum |author1=Ashfaquzzaman Syed |author2=Edwin D. Stevens |author3=Sandra G. Cruz | journal = Inorg. Chem. | year = 1984 | volume = 23 | issue = 22 | pages = 3673–3674 | doi = 10.1021/ic00190a053}} Further reading
4 : Organoplatinum compounds|Cod complexes|Chlorides|Chloro complexes |
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