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词条 Eudialyte group
释义

  1. List of the eudialyte-group minerals

     Approved species  Unnamed species  Other species 

  2. Further reading

  3. References

  4. External links

{{More footnotes|article|date=January 2014}}Eudialyte group is a group of complex trigonal zircono- and, more rarely, titanosilicate minerals with general formula [N(1)N(2)N(3)N(4)N(5)]3[M(1a)M(1b)]3M(2)3M(4)Z3[Si24O72]O'4X2, where N(1) and N(2) and N(3) and N(5) = Na+ and more rarely H3O+ or H2O, N(4) = Na+, Sr2+, Mn2+ and more rarely H3O+ or H2O or K+ or Ca2+ or REE3+ (rare earth elements), M(1) and M(1b) = Ca2+, M(1a) = Ca2+ or Mn2+ or Fe2+, M(2) = Fe (both II and III), Mn and rarely Na+, K+ or Zr4+, M(3) = Si, Nb and rarely W, Ti and [] (vacancy), M(4) = Si and or rarely [], Z Zr4+ and or rarely Ti4+, and X = OH−, Cl− and more rarely CO32− or F−. Some of the eudialyte-like structures can even be more complex, however, in general, its typical feature is the presence of [Si3O9]6− and [Si9O27]18− ring silicate groups. Space group is usually R3m or R-3m but may be reduced to R3 due to cation ordering.[1] Like other zirconosilicates, the eudialyte group minerals possess alkaline ion-exchange properties, as microporous materials.[2]

List of the eudialyte-group minerals

Approved species

  • Alluaivite - Na19(Ca,Mn)6(Ti,Nb)3Si26O74Cl.2H2O (space group R-3m)
  • Andrianovite - Na12(K,Sr,Ce)3Ca6Mn3Zr3NbSi(Si3O9)2(Si9O27)2O(O,H2O,OH)5 (space group R3m)
  • Aqualite - (H3O)8(Na,K,Sr)5Ca6Zr3Si26O66(OH)9Cl (space group R3)
  • Carbokentbrooksite - (Na,□)12(Na,Ce)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3).H2O (space group R3m)
  • Davinciite - Na12K3Ca6Fe32+Zr3(Si26O73OH)Cl2 (space group R3m)
  • Dualite - Na30(Ca,Na,Ce,Sr)12(Na,Mn,Fe,Ti)6Zr3Ti3Mn(Si51O144)(OH,H2O,Cl)9 (space group R3m)
  • Eudialyte - Na15Ca6(Fe,Mn)3Zr3(Si3O9) 2SiO(Si9O27)2(O,OH,H2O)3(OH,Cl)2 (space group R-3m)
  • Feklichevite - Na11Ca9(Fe3+,Fe2+)2Zr3Nb[Si25O73](OH,H2O,Cl,O)5 (space group R3m)
  • Fengchengite - Na12◻3(Ca,Sr)6Fe33+Zr3Si(Si25O73)(H2O,OH)3(OH,Cl)2 (space group R-3m)
  • Ferrokentbrooksite - Na15Ca6(Fe,Mn)3Zr3NbSi25O73(O,OH,H2O)3(Cl,F,OH)2 (space group R3m)
  • Georgbarsanovite - Na12(Mn,Sr,REE)3Ca6Fe3Zr3NbSi25O76Cl2.H2O (space group R3m)
  • Golyshevite - (Na10Ca3)Ca6Zr3Fe2SiNb(Si3O9)2(Si9O27)2(OH)3(CO3).H2O (space group R3m)
  • Ikranite - (Na,H3O)15(Ca,Mn)6Fe3+2Zr3-4SiO(Si3O9)2(Si9O27)2.2-3H2O (space group R3m)
  • Ilyukhinite (H3O,Na)14Ca6Mn2Zr3Si26O72(OH)2·3H2O - the most recent add (space group R3m)[3]
  • Johnsenite-(Ce) - Na12(Ce,La,Sr,Ca)3Ca6Mn3Zr3WSiO(Si3O9)2(Si9O27)2(CO3)(OH,Cl)2.H2O (space group R3m)
  • Kentbrooksite - (Na,REE)15(Ca,REE)6(Mn,Fe)3Zr3(Si3O9)2SiO(Si9O27)2(O,OH,H2O)3F2.2H2O (space group R3m)
  • Khomyakovite - Na12Sr3Ca6Fe3Zr3(W,Nb)SiO(Si3O9)2(Si9O27)2(O,OH,H2O)3(OH,Cl)2 (space group R3m)
  • Labyrinthite - (Na,K,Sr)35Ca12Fe3Zr6TiSi51O144(O,OH,H2O)9Cl3 (space group R3)
  • Manganokhomyakovite - Na12Sr3Ca6Mn3Zr3(W,Nb)SiO(Si3O9)2(Si9O27)2(O,OH,H2O)3(OH,Cl)2 (space group R3m)
  • Manganoeudialyte - Na14Ca6Mn3Zr3[Si26O72(OH)2]Cl2.4H2O (space group R3m)
  • Mogovidite - Na9(Ca,Na)5Ca6Zr3Fe2(SiNb)(Si3O9)2(Si9O27)2(CO3)(OH,H2O)3Cl0.3 (space group R3m)
  • Oneillite - Na15Ca3Mn3Fe2+3Zr3Nb(Si25O73)(O,OH,H2O)3(OH,Cl)2 (space group R3)
  • Raslakite - Na15Ca3Fe2+3(Na,Zr)3Zr3Nb<0.5SiO(Si3O9)2(Si9O27)2(OH,H2O)3(Cl,OH) (space group R3)
  • Rastsvetaevite - Na27K8Ca12Fe3Zr6Si52O144(O,OH,H2O)6Cl2 (space group R3m)
  • Taseqite - Na12Sr3Ca6Fe3Zr3NbSiO(Si3O9)2(Si9O27)2(O,OH,H2O)3Cl2 (space group R3m)
  • Voronkovite - Na15(Na,Ca,Ce)3(Mn,Ca)3Fe3Zr3Si26O72(OH,O)4Cl.H2O (space group R3)
  • Zirsilite-(Ce) - (Na,□)12(Ce,Na)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3).H2O (space group R3m)

Unnamed species

The list of eudialyte-related natural phases is growing. There are many such phases, some of them very complex, coded "UM" by the International Mineralogical Association, and include:[4][5]

  • UM-1971-22-SiO:CaClFeHMgMnNaNbZr - Na12Ca5(Ce,La,Y,Ca)Zr3(Zr,Nb)(Fe,Mn)3[Si9O24-26(OH)1-3]2(Si3O9)2Cl - with variable substitution of OH for oxygen
  • UM1990-79-SiO:CaClFeHMnNaNbREEZr - Na14Ca5(Mg,Ca,Mn)Zr3(Si3O9)2(Si9O27)2(Si,Nb,Al,Zr)2(Fe,Zr)3(Mn,Na,Ce,La,Y)(Na,H2O,K,Sr)(OH)4-5(OH,Cl) - first representative with magnesium-dominant site
  • UM1990-80- SiO:CaFeHMnNaNbREEZr - Na14Ca4(Mn,Ca)2Zr3(Si3O9)2(Si9O27)2(Si,Nb,Al,Zr)2(Fe,Mn,Al,Ti)3(Na,Ce,La,Y,Mn)(Na,H2O,K,Sr)(OH)7-8
  • UM1998-21-SiO:CaCeClHMnNaZr - Na16Ca6(Mn,Ce)3Zr3(Si3O9)2(Si9O27)2(OH,Cl)4
  • UM1999-36-SiO:CaCeHMnNaNbSrZr - Na17Mn3Ca2Zr3Si26O72(OH,F,Cl)4
  • UM2000-66-SiO:CaClFeHMnNaNbSrZr - Na12(Ca,Mn)6(Sr,Na,K)3(Fe,Mn)3(Zr,Nb)4Si25O66(OH,Cl)11
  • UM2003-39- SiO:CaClFeHHfNaNbSrTaTiZr - Na12(Na,K,Mn,Sr)2Ca5(Ca,Mn)(Zr,Hf)3(Fe,[],Ta)3(Si,Nb,W)(Si,Al,Ti)Si24O72(OH,O)33.5Cl•1.2H2O
  • UM2004-51-SiO:CaClFFeHNaNbTi' - Na16Ca6(Fe,Mn)3Zr3(Ti,Nb)Si26O72FCl0.5•nH2O
  • UM2006-17-SiO:CaClFFeHMnNaZr - Na15(Ca3Mn3)Zr3(Fe,Zr)3SiSi(Si3O9)2(Si9O27)2O2(OH,F,Cl)3•2H2O
  • UM2006-18-SiO:CaClFFeHMnNaZr - Na15Ca3(Mn,Fe)3Zr3(Zr,Na)3(Si,Nb)(S,Ti,Si)(Si3O9)2(Si9O27)2(O,OH)5(Cl,F,H2O) - with essential sulfur and with Zr dominant in two sites
  • UM2006-28-SiO:CaHMnNaZr - Na33Ca12Zr6Mn3(Mn,Nb,Ti)2Si50O132(O,OH)12(OH,H2O,Cl)10 - with double c unit cell dimension

In addition, there is "eudialyte 3248": Na29Ca12Zr6[Si48O132(O,OH)12]{[Na]4[Si]2}{[Mn]3[Mn,Nb,Ti]2}(OH,H2O,Cl)10, plus admixtures of Ce, Sr, Ba and Y, characterized by one S-dominant site (not shown in the simplified formula)[6]

Other species

Rastsvetaeva et al. (2015) describe a species tentatively called "hydrorastsvetaevite", with a formula (Na11(H3O)11K6(H2O)1.5Sr)Ca12Fe3Na2MnZr6Si52O144(OH)4.5Cl3.5.[7]

Further reading

  • {{cite journal |id={{INIST|13846139}} |last1=Ageeva |first1=O. A. |last2=Borutzky |first2=B. Ye |last3=Chukanov |first3=N. V. |last4=Sokolova |first4=M. N. |year=2002 |title=Alluaivite and genetic aspect of the forming of enriched in Ti eudialytes in Khibiny massif |journal=Zapiski Vserossijskogo Mineralogičeskogo Obŝestva |volume=131 |issue=1 |pages=99–106 |url=http://www.minsoc.ru/articles.php?id=34&mid=21311&eid=2131109}}
  • {{cite journal |doi=10.1134/S1075701508080060 |title=Andrianovite, Na12(K,Sr,Ce)3Ca6Mn3Zr3Nb(Si25O73)(O, H2O,OH)5, a new potassium-rich mineral species of the eudialyte group from the Khibiny alkaline Pluton, Kola Peninsula, Russia |year=2009 |last1=Khomyakov |first1=A. P. |last2=Nechelyustov |first2=G. N. |last3=Rastsvetaeva |first3=R. K. |last4=Rozenberg |first4=K. A. |journal=Geology of Ore Deposits |volume=50 |issue=8 |pages=705–12 |bibcode=2008GeoOD..50..705K}}
  • {{cite journal |bibcode=2007GeoOD..49..739K |title=Aqualite, a new mineral species of the eudialyte group from the Inagli alkaline pluton, Sakha-Yakutia, Russia, and the problem of oxonium in hydrated eudialytes |last1=Khomyakov |first1=A. P. |last2=Nechelyustov |volume=49 |year=2007 |pages=739–51 |journal=Geology of Ore Deposits |doi=10.1134/S1075701507080089 |first2=G. N. |first3=R. K. |issue=8 |last3=Rastsvetaeva}}
  • {{cite journal |id={{INIST|15861098}} |last1=Khomyakov |first1=A. P. |last2=Dusmatov |first2=V. D. |last3=G. |last4=Gula |first4=A. |last5=Ivaldi |first5=G. |last6=Nechelyustov |first6=G. N. |year=2003 |title=Zapiski Vserossijskogo mineralogičeskogo obŝestva |volume=132 |issue=5 |pages=40–51}}
  • {{cite journal |id={{INIST|20451408}} |last1=Khomyakov |first1=A. P. |last2=Nechelyustov |first2=G. N. |last3=Rastsvetaeva |first3=R. K. |year=2007 |title=Dualite, Na30(Ca,Na,Ce,Sr)12(Na,Mn,Fe,Ti)6Zr3Ti3MnSi51O144(OH,H2O,Cl)9, a new zircono-titanosilicate with a modular eudialyte-like structure from Lovozero alkaline massif, Kola Peninsula, Russia |journal=Zapiski Vserossijskogo Mineralogičeskogo Obŝestva |volume=136 |issue=4 |pages=31–42 |url=http://www.minsoc.ru/articles.php?id=34&mid=21364&eid=2136403}}
  • {{cite journal |doi=10.1007/s10631-005-0014-5 |title=Crystal structure of a niobium-deficient carbonate analogue of feklichevite |year=2005 |last1=Rozenberg |first1=K. A. |last2=Rastsvetaeva |first2=R. K. |last3=Chukanov |first3=N. V. |last4=Verin |first4=I. A. |journal=Doklady Chemistry |volume=400 |issue=4–6 |pages=25–9}}
  • {{cite journal |doi=10.1134/1.1996727 |title=Crystal structure of golyshevite |year=2005 |last1=Rozenberg |first1=K. A. |last2=Rastsvetaeva |first2=R. K. |last3=Chukanov |first3=N. V. |last4=Verin |first4=I. A. |journal=Crystallography Reports |volume=50 |issue=4 |pages=539–43 |bibcode=2005CryRp..50..539R}}
  • {{cite journal |doi=10.2113/gscanmin.41.1.55 |title=Ferrokentbrooksite, A New Member of the Eudialyte Group from Mont Saint-Hilaire, Quebec, Canada |year=2003 |last1=Johnsen |first1=O. |last2=Grice |first2=J. D. |last3=Gault |first3=R. A. |journal=The Canadian Mineralogist |volume=41 |issue=1 |pages=55–60}}
  • {{cite journal |first1=Paula C. |last1=Piilonen |first2=Andrew J. |last2=Locock |first3=Ralph |last3=Rowe |first4=T. Scott |last4=Ercit |year=2007 |title=New Mineral Names |journal=American Mineralogist |volume=92 |pages=703–7 |url=http://www.minsocam.org/msa/ammin/toc/Abstracts/2007_Abstracts/Apr07_Abstracts/Piilonen_p703_07.pdf |doi=10.2138/am.2007.488 |issue=4|bibcode=2007AmMin..92..703P }}
  • {{cite journal |id={{INIST|15861096}} |last1=Chukanov |first1=N. V. |last2=Pekov |first2=I. V. |last3=Zadov |first3=A. E. |last4=Korovushkin |first4=V. V. |last5=Ekimenkova |first5=I. A. |last6=Rastsvetaeva |first6=R. K. |year=2003 |title=Ikranite (Na,H3O)15(Ca,Mn,REE)6Fe3+2Zr3(□,Zr)(□,Si)Si24O66(O,OH)6Cl·nH2О and raslakite Na15Ca3Fe3(Na,Zr)3Zr3(Si,Nb)(Si25O73)(OH,H2O)3(Cl,OH) - the new eudialyte-group minerals from Lovozero massif, Kola Peninsula |journal=Zapiski Vserossijskogo Mineralogičeskogo Obŝestva |volume=132 |issue=5 |pages=22–33 |url=http://www.minsoc.ru/articles.php?id=34&mid=21325&eid=2132501}}
  • {{cite journal |id={{INIST|17777968}} |doi=10.2113/gscanmin.44.1.105 |title=Johnsenite-(Ce) : A new member of the eudialyte group from Mont Saint-Hilaire, Quebec, Canada |year=2006 |last1=Grice |first1=Joel D. |last2=Gault |first2=Robert A. |journal=The Canadian Mineralogist |volume=44 |issue=1 |pages=105–15}}
  • {{cite journal |first1=John L. |last1=Jambor |first2=Vladimir A. |last2=Kovalenker |first3=Andrew C. |last3=Roberts |year=2000 |title=New Mineral Names |journal=American Mineralogist |volume=85 |pages=873–7 |url=http://www.minsocam.org/MSA/AmMin/toc/Abstracts/2000_Abstracts/MJ00_Abstracts/Jambor_p873_00.pdf}}
  • {{cite journal |id={{INIST|18813948}} |last1=Khomyakov |first1=A. P. |last2=Nechelyustov |first2=G. N. |last3=Rastvetaeva |first3=R. K. |year=2006 |title=Labyrinthite (Na,K,Sr)35Ca12Fe3Zr6TiSi51·O144(O,OH,H2O)9Cl3, a new mineral with the modular eudialyte-like structure from Khibiny alkaline massif, Kola Peninsula Russia |journal=Zapiski Vserossijskogo Mineralogičeskogo Obŝestva |volume=135 |issue=2 |pages=38–49 |url=http://www.minsoc.ru/articles.php?id=34&mid=21352&eid=2135202}}
  • {{cite journal |first1=T. Scott |last1=Ercit |first2=Paula C. |last2=Piilonen |first3=Ralph |last3=Rowe |year=2007 |title=New Mineral Names |journal=American Mineralogist |volume=92 |pages=1539–42 |url=http://www.minsocam.org/msa/ammin/toc/Abstracts/2007_Abstracts/AS07_Abstracts/Ercit_p1539_07.pdf |doi=10.2138/am.2007.499 |issue=8–9|bibcode=2007AmMin..92.1539E }}
  • {{cite journal |first1=Ole |last1=Johnsen |first2=Joel D. |last2=Grice |first3=Robert A. |last3=Gault |year=1999 |title=Oneillite: a new Ca-deficient and REE-rich member of the eudialyte group from Mont Saint-Hilaire, Quebec, Canada |journal=The Canadian Mineralogist |volume=37 |pages=1295–301 |url=http://www.saint-hilaire.ca/abs/CM371295.htm}}
  • {{cite journal |id={{INIST|18813995}} |last1=Khomyakov |first1=A. P. |last2=Nechelyustov |first2=G. N. |last3=Arakcheeva |first3=A. V. |year=2006 |title=Rastsvetaevite Na27K8Ca12Fe3Zr6Si4[Si3O9]4[Si9O27]34(О,ОН,Н2О) 6Сl2, a new mineral with a modular eudialyte-like structure and crystal-chemical systematics of the eudialyte group |journal=Zapiski Vserossijskogo Mineralogičeskogo Obŝestva |volume=135 |issue=1 |pages=49–65 |url=http://www.minsoc.ru/articles.php?id=34&mid=21351&eid=2135103}}
  • {{cite journal |id={{INIST|15422915}} |doi=10.1127/0028-3649/2004/2004-0083 |title=Taseqite, a new member of the eudialyte group from the Ilímaussaq alkaline complex, South Greenland |year=2004 |last1=Petersen |first1=O. V. |last2=Johnsen |first2=O. |last3=Gault |first3=R. A. |last4=Niedermayr |first4=G. |last5=Grice |first5=J. D. |journal=Neues Jahrbuch für Mineralogie - Monatshefte |volume=2004 |issue=2 |pages=83–96}}
  • Rastsvetaeva, R. K.; Chukanov, N. V.; Zaitsev, V. A.; Aksenov, S. M.; Viktorova, K. A. (2018-05). "[https://link.springer.com/content/pdf/10.1134%2FS1063774518030240.pdf Crystal Structure of Cl-Deficient Analogue of Taseqite from Odikhincha Massif]". Crystallography Reports. 63 (3): 349–357. doi:10.1134/s1063774518030240. ISSN 1063-7745

References

1. ^{{cite journal |doi=10.2113/gscanmin.41.3.785 |title=The Nomenclature of Eudialyte-Group Minerals |year=2003 |last1=Johnsen |first1=O. |last2=Ferraris |first2=G. |last3=Gault |first3=R. A. |last4=Grice |first4=J. D. |last5=Kampf |first5=A. R. |last6=Pekov |first6=I. V. |journal=The Canadian Mineralogist |volume=41 |issue=3 |pages=785–794}}
2. ^{{cite book |doi=10.1007/978-3-540-77123-4_6 |title=Mixed-Framework Microporous Natural Zirconosilicates : Minerals as Advanced Materials I |year=2008 |last1=Zubkova |first1=Natalia V. |last2=Pushcharovsky |first2=Dmitrii Yu. |isbn=978-3-540-77122-7 |pages=45–56}}
3. ^{{Cite journal | url=http://minmag.geoscienceworld.org/content/79/7/1859.extract | doi=10.1180/minmag.2015.079.7.18| title=New minerals and nomenclature modifications approved in 2015| journal=Mineralogical Magazine| volume=79| issue=7| pages=1859–1864| year=2015| last1=Hålenius| first1=U.| last2=Hatert| first2=F.| last3=Pasero| first3=M.| last4=Mills| first4=S. J.}}
4. ^Mindat, www.mindat.org
5. ^Smith, D.G.W., and Nickel, E.H.N., 2007. A System of Codification forUnnamed Minerals: Report of the SubCommittee for Unnamed Minerals of the IMA Commission on New Minerals, Nomenclature and Classification.Canadian Mineralogist v. 45, p.983-1055; http://nrmima.nrm.se/Valid2012.pdf
6. ^Rastsvetaeva et al. 2006, in: Ercit et al. 2007, https://link.springer.com/article/10.1134/S1028334X06070166
7. ^{{cite journal | doi=10.1134/S1063774515060279 | volume=60 | issue=6 | title=Crystal structure and genesis of the hydrated analog of rastsvetaevite | journal=Crystallography Reports | pages=831–840| bibcode=2015CryRp..60..831R |last1 = Rastsvetaeva|first1 = R. K.| last2=Aksenov | first2=S. M. | last3=Rozenberg | first3=K. A. | year=2015 }}

External links

  • Mindat.org
  • The Eudialyte homepage

3 : Cyclosilicates|Zirconium minerals|Sodium minerals
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