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词条 Isotopes of astatine
释义

  1. Alpha decay

  2. List of isotopes

      Notes  

  3. See also

  4. Notes

  5. References

  6. Bibliography

{{infobox astatine isotopes}}

Astatine (85At) has 39 known isotopes, all of which are radioactive; the range of their mass numbers is from 191 to 229. There also exist 23 metastable excited states. The longest-lived isotope is 210At, which has a half-life of 8.1 hours; the longest-lived isotope existing in naturally occurring decay chains is 219At with a half-life of 56 seconds.

Alpha decay

{{Astatine decay characteristics}}

Astatine has 23 nuclear isomers (nuclei with one or more nucleons – protons or neutrons – in an excited state). A nuclear isomer may also be called a "meta-state"; this means the system has more internal energy than the "ground state" (the state with the lowest possible internal energy), making the former likely to decay into the latter. There may be more than one isomer for each isotope. The most stable of them is astatine-202m1,{{efn|"m1" means that this state of the isotope is the next possible one above – energy greater than – the ground state. "m2" and similar designations refer to further higher energy states. The number may be dropped if there is only one well-established meta state, such as astatine-216m. Note that other designation techniques exist.}} which has a half-life of about 3 minutes; this is longer than those of all ground states except those of isotopes 203–211 and 220. The least stable one is astatine-214m1; its half-life of 265 ns is shorter than those of all ground states except that of astatine-213.[1]

Alpha decay energy follows the same trend as for other heavy elements.{{sfn|Lavrukhina|Pozdnyakov|1966|p=232}} Lighter astatine isotopes have quite high energies of alpha decay, which become lower as the nuclei become heavier. However, astatine-211 has a significantly higher energy than the previous isotope; it has a nucleus with 126 neutrons, and 126 is a magic number (corresponding to a filled neutron shell). Despite having a similar half-life time as the previous isotope (8.1 hours for astatine-210 and 7.2 hours for astatine-211), the alpha decay probability is much higher for the latter: 41.8 percent versus just 0.18 percent.[1]{{efn|This means that if decay modes other than alpha are omitted, then astatine-210 has an alpha half-life of 4,628.6 hours (128.9 days) and astatine-211 has one of 17.2 hours (0.9 days). Therefore, astatine-211 is less stable toward alpha decay than the lighter isotope, and is more likely to undergo alpha decay in the same time period.}} The two following isotopes release even more energy, with astatine-213 releasing the highest amount of energy of all astatine isotopes. For this reason, it is the shortest-lived astatine isotope.{{sfn|Lavrukhina|Pozdnyakov|1966|p=232}} Even though heavier astatine isotopes release less energy, no long-lived astatine isotope exists; this happens due to the increasing role of beta decay.{{sfn|Lavrukhina|Pozdnyakov|1966|p=232}} This decay mode is especially important for astatine: as early as 1950, it was postulated that the element has no beta-stable isotopes (i.e., ones that do not undergo beta decay at all),[2] though nuclear mass measurements reveal that 215At is in fact beta-stable, as it has the lowest mass of all isobars with A = 215.[3] A beta decay mode has been found for all other astatine isotopes except for astatine-213, astatine-214, and astatine-216m.[1] Among other isotopes: astatine-210 and the lighter isotopes decay by positron emission); astatine-216 and the heavier isotopes undergo beta decay; astatine-212 can decay either way; and astatine-211 decays by electron capture instead.[1]

The most stable isotope of astatine is At-210, which has a half-life of about 8.1 hours. This isotope's primary decay mode is positron emission to the relatively long-lived alpha emitter, polonium-210. In total, only five isotopes of astatine have half-lives exceeding one hour: those between 207 and 211. The least stable ground state isotope is astatine-213, with a half-life of about 125 nanoseconds. It undergoes alpha decay to the extremely long-lived isotope (in practice, a stable one) bismuth-209.[1]

List of isotopes

nuclide
symbol
Z(p) N(n)  
isotopic mass (u)
 
half-lifedecay
mode(s)[4][5]
daughter
isotope(s)
nuclear
spin and
parity
representative
isotopic
composition
(mole fraction)
range of natural
variation
(mole fraction)
excitation energy
191At85106 1.7(+11−5) ms (1/2+)
191mAt 2.1(+4−3) ms (7/2−)
192At85107192.00314(28)11.5(0.6) ms α (99.79%) 188Bi3+#
β+, SF (0.21%) (various)
192mAt330(90)# keV88(6) ms α (99.79%) 188mBi(9-, 10−)
β+, SF (0.21%) (various)
193At85108 192.99984(6) 28(+5−4) ms α 189Bi (1/2+)
193m1At50 keV 21(5) ms (7/2−)
193m2At39 keV 27(+4−5) ms (13/2+)
194At85109193.99873(20)286(7) ms α 190Bi(4-, 5-)
β+ (rare) 194Po
194mAt480(190) keV323(7) ms α 190Bi(9-, 10-)
IT (rare) 194At
195At85110194.996268(10)328(20) ms α (75%) 191Bi(1/2+)
β+ (25%) 195Po
195mAt34(7) keV 147(5) ms (7/2-)
196At85111195.99579(6)253(9) ms α (96%) 192Bi(3+)
β+ (4.0%) 196Po
196m1At−30(80) keV 20# ms (10−)
196m2At157.9(1) keV 11 µs (5+)
197At85112196.99319(5)0.390(16) s α (96%) 193Bi(9/2−)
β+ (4.0%) 197Po
197mAt52(10) keV 2.0(2) s (1/2+)
198At85113197.99284(5)4.2(3) s α (94%) 194Bi(3+)
β+ (6%) 198Po
198mAt330(90)# keV 1.0(2) s (10−)
199At85114198.99053(5)6.92(13) s α (89%) 195Bi(9/2−)
β+ (11%) 199Po
200At85115199.990351(26)43.2(9) s α (57%) 196Bi(3+)
β+ (43%) 200Po
200m1At112.7(30) keV47(1) s α (43%) 196Bi(7+)
IT 200At
β+ 200Po
200m2At344(3) keV 3.5(2) s (10−)
201At85116200.988417(9)85(3) s α (71%) 197Bi(9/2−)
β+ (29%) 201Po
202At85117201.98863(3)184(1) s β+ (88%) 202Po(2,3)+
α (12%) 198Bi
202m1At190(40) keV 182(2) s (7+)
202m2At580(40) keV 460(50) ms (10−)
203At85118202.986942(13)7.37(13) min β+ (69%) 203Po9/2−
α (31%) 199Bi
204At85119203.987251(26)9.2(2) min β+ (96%) 204Po7+
α (3.8%) 200Bi
204mAt587.30(20) keV 108(10) ms IT 204At (10−)
205At85120204.986074(16)26.2(5) min β+ (90%) 205Po9/2−
α (10%) 201Bi
205mAt2339.65(23) keV 7.76(14) µs 29/2+
206At85121205.986667(22)30.6(13) min β+ (99.11%) 206Po(5)+
α (0.9%) 202Bi
206mAt807(3) keV 410(80) ns (10)−
207At85122206.985784(23)1.80(4) h β+ (91%) 207Po9/2−
α (8.6%) 203Bi
208At85123207.986590(28)1.63(3) h β+ (99.5%) 208Po6+
α (0.55%) 204Bi
209At85124208.986173(8)5.41(5) h β+ (96%) 209Po9/2−
α (4.0%) 205Bi
210At85125209.987148(8)8.1(4) h β+ (99.8%) 210Po(5)+
α (0.18%) 206Bi
210m1At2549.6(2) keV 482(6) µs (15)−
210m2At4027.7(2) keV 5.66(7) µs (19)+
211At85126210.9874963(30)7.214(7) h EC (58.2%) 211Po9/2−
α (42%) 207Bi
212At85127211.990745(8)0.314(2) s α (99.95%) 208Bi(1−)
β+ (0.05%) 212Po
β (2×10−6%) 212Rn
212m1At223(7) keV0.119(3) s α (99%) 208Bi(9−)
IT (1%) 212At
212m2At4771.6(11) keV 152(5) µs (25−)
213At85128 212.992937(5) 125(6) ns α 209Bi 9/2−
214At85129 213.996372(5) 558(10) ns α 210Bi 1−
214m1At59(9) keV 265(30) ns
214m2At231(6) keV 760(15) ns 9−
215At85130 214.998653(7) 0.10(2) ms α 211Bi 9/2− Trace[6]
216At85131216.002423(4)0.30(3) ms α (99.99%) 212Bi1−
β (.006%) 216Rn
EC (3×10−7%) 216Po
216mAt413(5) keV 100# µs (9−)
217At85132217.004719(5)32.3(4) ms α (99.98%) 213Bi9/2−
β (.012%) 217Rn
218At85133218.008694(12)1.5(3) s α (99.9%) 214Bi1−#Trace[7]
β (0.10%) 218Rn
219At85134219.011162(4)56(3) s α (97%) 215Bi(9/2-)Trace[6]
β (3.0%) 219Rn
220At85135220.01541(6)3.71(4) min β (92%) 220Rn3(−#)
α (8.0%) 216Bi
221At85136 221.01805(21)# 2.3(2) min β 221Rn 3/2−#
222At85137 222.02233(32)# 54(10) s β 222Rn
223At85138 223.02519(43)# 50(7) s β 223Rn 3/2−#
224At85139 224.02975(22)# 2.5(1.5) min β 224Rn
1. ^{{NUBASE 2003}}
2. ^{{cite book|title=Isotope geology|edition=2nd|publisher=Pergamon Press|pages=403|year=1956 | isbn = 978-0-470-70800-2 |first=Kalervo|last=Rankama}}
3. ^{{Nubase 2016}}
4. ^{{cite web |url=http://www.nucleonica.net/unc.aspx |title=Universal Nuclide Chart |publisher=nucleonica |registration=yes}}
5. ^Abbreviations:
EC: electron capture
IT: isomeric transition
SF:spontaneous fission
6. ^Intermediate decay product of 235U
7. ^Intermediate decay product of 238U

Notes

  • Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
  • Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic masses from IUPAC, which use expanded uncertainties.

See also

{{Wikipedia-Books|Astatine}}{{-}}

Notes

References

  • {{cite journal|last=Audi|first=G.|last2=Kondev|first2=F.G.|last3=Wang|first3=M.|last4=Huang|first4=W.J.| last5=Naimi|first5=S.|title=The NUBASE2016 evaluation of nuclear properties|url=http://amdc.in2p3.fr/nubase/2017Audi03.pdf|journal=Chinese Physics C|volume=41|issue=3|date=2017|pages=030001|doi=10.1088/1674-1137/41/3/030001}}
  • Isotope masses from:
    • {{NUBASE 2003}}
  • Isotopic compositions and standard atomic masses from:
    • {{CAWIA 2003}}
    • {{CIAAW 2005}}
  • Half-life, spin, and isomer data selected from the following sources. See editing notes on this article's talk page.
    • {{NUBASE 2003}}
    • {{NNDC}}
    • {{CRC85|chapter=11}}

Bibliography

  • {{cite book | script-title=ru:Аналитическая химия технеция, прометия, астатина и франция |trans-title=Analytical Chemistry of Technetium, Promethium, Astatine, and Francium | first1 = A K | last1 = Lavrukhina | first2 = A A | last2 = Pozdnyakov | year = 1966 | publisher = Nauka | ref = harv | language = Russian }}
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2 : Isotopes of astatine|Lists of isotopes by element

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