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词条 Isotopes of polonium
释义

  1. Polonium-210

  2. List of isotopes

      Notes  

  3. References

  4. See also

{{infobox polonium isotopes}}Polonium (84Po) has 42 isotopes, all of which are radioactive, with between 186 and 227 nucleons. 210Po with a half-life of 138.376 days has the longest half-life of naturally occurring polonium. 209Po with a half-life of 125 years has the longest half-life of all isotopes of polonium. 209Po and 208Po (half-life 2.9 years) can be made through proton bombardment of bismuth in a cyclotron.[1]

Polonium-210

210Po is an alpha emitter that has a half-life of 138.376 days; it decays directly to stable 206Pb. A milligram of 210Po emits as many alpha particles per second as 5 grams of 226Ra.[2] A few curies (1 curie equals 37 gigabecquerels) of 210Po emit a blue glow caused by excitation of surrounding air. A single gram of 210Po generates 140 watts of power.[3] Because it emits many alpha particles, which are stopped within a very short distance in dense media and release their energy, 210Po has been used as a lightweight heat source to power thermoelectric cells in artificial satellites; for instance, a 210Po heat source was also in each of the Lunokhod rovers deployed on the surface of the Moon, to keep their internal components warm during the lunar nights.[4] Some anti-static brushes, used for neutralizing static electricity on materials like photographic film, contain a few microcuries of 210Po as a source of charged particles.[5] 210Po was also used in initiators for atomic bombs through the (α,n) reaction with beryllium{{citation needed|date=February 2017}}.

The majority of the time 210Po decays by emission of an alpha particle only, not by emission of an alpha particle and a gamma ray. About one in 100,000 decays results in the emission of a gamma ray.[6] This low gamma ray production rate makes it more difficult to find and identify this isotope. Rather than gamma ray spectroscopy, alpha spectroscopy is the best method of measuring this isotope.

210Po occurs in minute amounts in nature, where it is an intermediate isotope in the uranium series decay chain. It is generated via beta decay from 210Pb and 210Bi. In the environment, 210Po can accumulate in seafood.[7]210Po is extremely toxic, with one microgram being enough to kill the average adult (250,000 times more toxic than hydrogen cyanide by weight).[8] 210Po was used to kill Russian dissident and ex-FSB officer Alexander V. Litvinenko in 2006,[9] and was suspected as a possible cause of Yasser Arafat's death, following exhumation and analysis of his corpse in 2012–2013.[10]

List of isotopes

nuclide
symbol
historic
name
Z(p)
[11][12]
N(n)
[11][12]
isotopic mass (u)
[13]
half-life
[14][15][16]
decay
mode(s)
[17][18]
daughter
isotope(s)
[19]
nuclear
spin and
parity[13][15][16]
representative
isotopic
composition
(mole fraction)
range of natural
variation
(mole fraction)
excitation energy
186Po84102 186.0044(18) 34(12) µs
α 182Pb 0+
187Po84103 187.00304(30) 1.40(0.25) ms
α 183Pb (1/2-, 5/2-)
187mPo4(27) keV 0.5 ms 13/2+#
188Po84104 187.999422(21) 430(180) µs
[0.40(+20−15) ms]
α 184Pb 0+
189Po84105 188.998481(24) 5(1) ms α 185Pb 3/2−#
190Po84106189.995101(14)2.46(5) ms α (99.9%) 186Pb0+
β+ (.1%) 190Bi
191Po84107190.994574(12)22(1) ms α 187Pb3/2−#
β+ (rare) 191Bi
191mPo130(21) keV 93(3) ms (13/2+)
192Po84108191.991335(13)32.2(3) ms α (99%) 188Pb0+
β+ (1%) 192Bi
192mPo2600(500)# keV ~1 µs 12+#
193Po84109192.99103(4)420(40) ms
[370(+46−40) ms]
α 189Pb3/2−#
β+ (rare) 193Bi
193mPo100(30)# keV240(10) ms
[243(+11−10) ms]
α 189Pb(13/2+)
β+ (rare) 193Bi
194Po84110193.988186(13)0.392(4) s α 190Pb0+
β+ (rare) 194Bi
194mPo2525(2) keV 15(2) µs (11−)
195Po84111194.98811(4)4.64(9) s α (75%) 191Pb3/2−#
β+ (25%) 195Bi
195mPo110(50) keV1.92(2) s α (90%) 191Pb13/2+#
β+ (10%) 195Bi
IT (.01%) 195Po
196Po84112195.985535(14)5.56(12) s α (94%) 192Pb0+
β+ (6%) 196Bi
196mPo2490.5(17) keV 850(90) ns (11−)
197Po84113196.98566(5)53.6(10) s β+ (54%) 197Bi(3/2−)
α (44%) 193Pb
197mPo230(80)# keV25.8(1) s α (84%) 193Pb(13/2+)
β+ (16%) 197Bi
IT (.01%) 197Po
198Po84114197.983389(19)1.77(3) min α (57%) 194Pb0+
β+ (43%) 198Bi
198m1Po2565.92(20) keV 200(20) ns 11−
198m2Po2691.86(20) keV 750(50) ns 12+
199Po84115198.983666(25)5.48(16) min β+ (92.5%) 199Bi(3/2−)
α (7.5%) 195Pb
199mPo312.0(28) keV4.17(4) min β+ (73.5%) 199Bi13/2+
α (24%) 195Pb
IT (2.5%) 199Po
200Po84116199.981799(15)11.5(1) min β+ (88.8%) 200Bi0+
α (11.1%) 196Pb
201Po84117200.982260(6)15.3(2) min β+ (98.4%) 201Bi3/2−
α (1.6%) 197Pb
201mPo424.1(24) keV8.9(2) min IT (56%) 201Po13/2+
EC (41%) 201Bi
α (2.9%) 197Pb
202Po84118201.980758(16)44.7(5) min β+ (98%) 202Bi0+
α (2%) 198Pb
202mPo2626.7(7) keV >200 ns 11−
203Po84119202.981420(28)36.7(5) min β+ (99.89%) 203Bi5/2−
α (.11%) 199Pb
203m1Po641.49(17) keV45(2) s IT (99.96%) 203Po13/2+
α (.04%) 199Pb
203m2Po2158.5(6) keV >200 ns
204Po84120203.980318(12)3.53(2) h β+ (99.33%) 204Bi0+
α (.66%) 200Pb
205Po84121204.981203(21)1.66(2) h β+ (99.96%) 205Bi5/2−
α (.04%) 201Pb
205m1Po143.166(17) keV 310(60) ns 1/2−
205m2Po880.30(4) keV 645 µs 13/2+
205m3Po1461.21(21) keV 57.4(9) ms IT 205Po 19/2−
205m4Po3087.2(4) keV 115(10) ns 29/2−
206Po84122205.980481(9)8.8(1) d β+ (94.55%) 206Bi0+
α (5.45%) 202Pb
206m1Po1585.85(11) keV 222(10) ns (8+)#
206m2Po2262.22(14) keV 1.05(6) µs (9−)#
207Po84123206.981593(7)5.80(2) h β+ (99.97%) 207Bi5/2−
α (.021%) 203Pb
207m1Po68.573(14) keV 205(10) ns 1/2−
207m2Po1115.073(16) keV 49(4) µs 13/2+
207m3Po1383.15(6) keV 2.79(8) s IT 207Po 19/2−
208Po84124207.9812457(19)2.898(2) y α (99.99%) 204Pb0+
β+ (.00277%) 208Bi
209Po84125208.9824304(20)125.2(3.3) y[20] α (99.52%) 205Pb1/2−
β+ (.48%) 209Bi
210Po Radium F84126 209.9828737(13) 138.376(2) d α 206Pb 0+ Trace[21]
210mPo5057.61(4) keV 263(5) ns 16+
211Po Actinium C'84127 210.9866532(14) 0.516(3) s α 207Pb 9/2+ Trace[22]
211m1Po1462(5) keV25.2(6) s α (99.98%) 207Pb(25/2+)
IT (.016%) 211Po
211m2Po2135.7(9) keV 243(21) ns (31/2−)
211m3Po4873.3(17) keV 2.8(7) µs (43/2+)
212Po Thorium C'84128 211.9888680(13) 299(2) ns α 208Pb 0+ Trace[23]
212mPo2911(12) keV45.1(6) s α (99.93%) 208Pb(18+)
IT (.07%) 212Po
213Po84129 212.992857(3) 3.65(4) µs α 209Pb 9/2+
214Po Radium C'84130 213.9952014(16) 164.3(20) µs α 210Pb 0+ Trace[21]
215PoActinium A84131214.9994200(27)1.781(4) ms α (99.99%) 211Pb9/2+Trace[22]
β (2.3×10−4%) 215At
216PoThorium A84132216.0019150(24)0.145(2) s α 212Pb0+Trace[23]
ββ (rare) 216Rn
217Po84133217.006335(7)1.47(5) s α (95%) 213Pb5/2+#
β (5%) 217At
218PoRadium A84134218.0089730(26)3.10(1) min α (99.98%) 214Pb0+Trace[21]
β (.02%) 218At
219Po84135219.01361(16)10.3(1) min α (28.2%) 215Pb9/2+#
β (71.8%) 219At
220Po84136 220.0164(18) 40# s
[>300 ns]
β 220At 0+
221Po84137 221.02123(20) 2.2(0.7) min β 221At 9/2+#
222Po84138 222.024144(40) 9.1(7.2) min β 222At 0+
1. ^{{Cite book| last=Carvalho|first=F.|last2=Fernandes|first2=S.|last3=Fesenko|first3=S. |last4=Holm|first4=E.|last5=Howard|first5=B.|last6=Martin|first6=P.|last7=Phaneuf|first7=P. |last8=Porcelli|first8=D.|last9=Pröhl|first9=G.|last10=Twining|first10=J.|title=The Environmental Behaviour of Polonium|series=Technical reports series|volume=484|publisher=International Atomic Energy Agency|location=Vienna|date=2017|page=22|issn=0074-1914|isbn=978-92-0-112116-5}}
2. ^{{cite web |title=The Elements |author=C. R. Hammond |publisher=Fermi National Accelerator Laboratory |pages=4–22 |url=http://www-d0.fnal.gov/hardware/cal/lvps_info/engineering/elements.pdf}}
3. ^{{Cite web|url = http://www.ead.anl.gov/pub/doc/polonium.pdf|title = Polonium|date = |accessdate = |website = |publisher = Argonne National Laboratory|last = |first = |archiveurl = https://web.archive.org/web/20120310145431/http://www.ead.anl.gov/pub/doc/polonium.pdf|archivedate = 2012-03-10}}
4. ^Andrew Wilson, Solar System Log, (London: Jane's Publishing Company Ltd, 1987), p. 64.
5. ^{{cite web |publisher=Company 7 |title=Staticmaster Alpha Ionizing Brush |url=http://www.company7.com/staticmaster/products/staticmaster.html}}
6. ^210PO A DECAY {{webarchive|url=https://web.archive.org/web/20150224043744/http://atom.kaeri.re.kr/cgi-bin/decay?Po-210+A |date=February 24, 2015 }}
7. ^{{cite journal |last1=Richter |first1=F. |last2=Wagmann |first2=M. |last3=Zehringer |first3=M. |title=Polonium – on the Trace of a Powerful Alpha Nuclide in the Environment |journal=CHIMIA International Journal for Chemistry |date=2012 |volume=66 |issue=3 |pages=131 |doi=10.2533/chimia.2012.131 |url=https://www.researchgate.net/publication/224869922_Polonium_-_on_the_Trace_of_a_Powerful_Alpha_Nuclide_in_the_Environment}}
8. ^{{cite web|last1=Sublette|first1=Carey|title=Polonium Poisoning|url=http://nuclearweaponarchive.org/News/PoloniumPoison.html}}
9. ^{{cite news |first=Alan |last=Cowell |date=November 24, 2006 |title=Radiation Poisoning Killed Ex-Russian Spy |url=https://www.nytimes.com/2006/11/24/world/europe/25spycnd.html |work=The New York Times}}
10. ^{{cite web|title=Arafat's death: what is Polonium-210?|url=http://www.aljazeera.com/video/asia-pacific/2012/07/2012746748407858.html|work=Al Jazeera|date=July 10, 2012}}
11. ^{{CAWIA 2003}}
12. ^{{CIAAW 2005}}
13. ^{{NUBASE 2003}}
14. ^{{NUBASE 2016}}
15. ^{{NNDC}}
16. ^{{CRC85|chapter=11}}
17. ^{{cite web |url=http://www.nucleonica.net/unc.aspx |title=Universal Nuclide Chart |publisher=nucleonica |registration=yes}}
18. ^Abbreviations:
EC: Electron capture
IT: Isomeric transition
19. ^Bold for stable isotopes, bold italics for nearly stable isotopes (half-life longer than the age of the universe)
20. ^{{cite web|last1=Boutin|first1=Chad|title=Polonium's Most Stable Isotope Gets Revised Half-Life Measurement|url=https://www.nist.gov/pml/div682/po-090914.cfm|website=nist.gov|publisher=NIST Tech Beat|accessdate=9 September 2014|date=2014-09-09}}
21. ^Intermediate decay product of Uranium-238
22. ^Intermediate decay product of Uranium-235
23. ^Intermediate decay product of Thorium-232

Notes

  • Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
  • Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC, which use expanded uncertainties.
  • Half-life abbreviations are y=year, d=day, min=minute, s=second, ms=millisecond, µs=microsecond, ns=nanosecond.
  • A superscripted m (or m2, etc.) refers to an isomer of that particular isotope.

References

{{Citations broken|section|date=November 2013}}

See also

  • Poisoning of Alexander Litvinenko
{{Navbox element isotopes}}

3 : Polonium|Isotopes of polonium|Lists of isotopes by element

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