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词条 Indophenol
释义

  1. Berthelot test

  2. Related compounds

  3. References

{{chembox
| verifiedrevid = 400118162
| ImageFile=Indophenol.svg
| ImageFile1 = Indophenol-3D-spacefill.png
| ImageAlt1 = Indophenol molecule
| ImageFile2 = Indophenol.jpg
| ImageSize=220
| IUPACName=4-(4-hydroxyphenyl)iminocyclohexa-2,5-dien-1-one
| OtherNames=Benzenoneindophenol, phenolindophenol[1]
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 9951
| InChI = 1/C12H9NO2/c14-11-5-1-9(2-6-11)13-10-3-7-12(15)8-4-10/h1-8,14H
| InChIKey = RSAZYXZUJROYKR-UHFFFAOYAS
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/C12H9NO2/c14-11-5-1-9(2-6-11)13-10-3-7-12(15)8-4-10/h1-8,14H
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = RSAZYXZUJROYKR-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|correct|??}}
| CASNo=500-85-6
| PubChem=10379
| SMILES = O=C/2/C=C\\C(=N\\c1ccc(O)cc1)\\C=C\\2
}}
|Section2={{Chembox Properties
| C=12 | H=9 | N=1 | O=2
| Appearance=Reddish-blue powder[1]
| Density=
| MeltingPt= above 300 °C
| MeltingPt_ref =[1]
| BoilingPt=
| Solubility=
|Section3={{Chembox Hazards
| MainHazards=
| FlashPt=
| AutoignitionPt =
}}Indophenol is an organic compound with the formula OC6H4NC6H4OH. It is deep blue dye that is the product of the Berthelot's reaction, a common test for ammonia.[2] The indophenol group, with various substituents in place of OH and various ring substitutions, is found in many dyes used in hair coloring and textiles.[3]

Indophenol is used in hair dyes, lubricants, redox materials, liquid crystal displays, fuel cells and chemical-mechanical polishing. It is an environmental pollutant and is toxic to fish.[1]

Berthelot test

In the Berthelot test (1859), a sample suspected of having containing ammonia is treated with sodium hypochlorite and phenol. The formation of indophenol is used to determine ammonia and paracetamol by spectrophotometry.[4] Other phenols can be used. Dichlorophenol-indophenol (DCPIP), a form of indophenol, is often used to determine the presence of vitamin C (ascorbic acid).[5]

Related compounds

Indophenol blue is a different compound with systematic name N-(p-dimethylaminophenyl)-1,4-naphthoquinoneimine.[6]

{{clear-left}}

References

{{Commons category|Indophenol}}
1. ^{{cite book|author=Sabnis, R. W. |title=Handbook of Acid-Base Indicators|url=https://books.google.com/books?id=EzDbTL9Oah0C&pg=PA196|date=2007|publisher=CRC Press|isbn=978-0-8493-8219-2|page=196}}
2. ^{{cite journal|doi=10.1021/ac50011a034|title=Spectrophotometric and kinetics investigation of the Berthelot reaction for the determination of ammonia|journal=Analytical Chemistry|volume=49|issue=3|pages=464–469|year=1977|last1=Patton|first1=Charles J.|last2=Crouch|first2=S. R.}}
3. ^{{cite encyclopedia|author=Horst Berneth|encyclopedia=Ullmann's Encyclopedia of Industrial Chemistry|year=2002|publisher=Wiley-VCH|place=Weinheim|doi=10.1002/14356007.a03_213.pub2|isbn=978-3527306732|chapter=Azine Dyes}}
4. ^{{cite journal|pmid=12400662|year=2002|last1=Tsuboi|first1=T.|title=Sensitivity improvement of ammonia determination based on flow-injection indophenol spectrophotometry with manganese(II) ion as a catalyst and analysis of exhaust gas of thermal power plant|journal=Analytical Sciences : The International Journal of the Japan Society for Analytical Chemistry|volume=18|issue=10|pages=1141–4|last2=Hirano|first2=Y.|last3=Shibata|first3=Y.|last4=Motomizu|first4=S.}}
5. ^{{cite journal|doi=10.1002/jps.2600720208|title=Titrimetric Determination of Ascorbic Acid with 2,6-Dichlorophenol Indophenol in Commercial Liquid Diets|journal=Journal of Pharmaceutical Sciences|volume=72|issue=2|pages=126–129|year=1983|last1=Hughes|first1=David Emlyn}}
6. ^{{cite journal|doi=10.1126/science.139.3557.835 |title=Indophenol Blue as a Chromogenic Agent for Identification of Halogenated Aromatic Hydrocarbons |journal=Science |volume=139 |issue=3557 |pages=835–836 |year=1963 |last1=Graham |first1=S. O. |bibcode=1963Sci...139..835G }}

1 : Indophenol dyes

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