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词条 Iodine trifluoride
释义

  1. Reactions

  2. Chemical properties

  3. References

{{Redirect|IF3}}{{chembox
| Watchedfields = changed
| verifiedrevid = 446239261
| ImageFile = Iodine trifluoride.svg
| ImageSize = 150px
| ImageName = Structural formula
| ImageFile1 = Iodine-trifluoride-3D-spacefill.png
| ImageSize1 = 160
| ImageAlt1 = Iodine trifluoride molecule
| IUPACName = Iodine trifluoride
| OtherNames = iodine(III) fluoride
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 10329096
| InChI = 1/F3I/c1-4(2)3
| InChIKey = VJUJMLSNVYZCDT-UHFFFAOYAM
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/F3I/c1-4(2)3
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = VJUJMLSNVYZCDT-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 22520-96-3
| PubChem = 13932268
| SMILES = FI(F)F
}}
|Section2={{Chembox Properties
| Formula = IF3
| MolarMass = 183.9 g/mol
| Appearance = yellow solid
| Density =
| MeltingPt = decomposes above −28 °C
| BoilingPt =
| Solubility = }}
|Section3={{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt = }}
|Section4={{Chembox Related
| OtherAnions = iodine trichloride
| OtherCations = bromine trifluoride
| OtherCompounds = chlorine trifluoride
iodine pentafluoride }}
}}

Iodine trifluoride is an interhalogen compound with the chemical formula IF3. It is a yellow solid which decomposes above −28 °C. It can be synthesised from the elements, but care must be taken to avoid the formation of IF5.

Reactions

F2 reacts with I2 to yield IF3 at −45 °C in CCl3F. Alternatively, at low temperatures, the fluorination reaction I2 + 3XeF2 → 2IF3 + 3Xe can be used. Not much is known about iodine trifluoride as it is so unstable.

Chemical properties

Iodine trifluoride has five electron pairs, and like chlorine trifluoride is T-shaped as predicted by VSEPR Theory.[1]

References

1. ^{{Greenwood&Earnshaw2nd}}
{{Iodine compounds}}

3 : Fluorides|Interhalogen compounds|Iodine compounds

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