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词条 Karl Friedrich Mohr
释义

  1. Life

  2. Work

  3. Selected writings

  4. References

  5. Further reading

Karl Friedrich Mohr (November 4, 1806 – September 28, 1879) was a German chemist famous for his early statement of the principle of the conservation of energy. Ammonium iron(II) sulfate, (NH4)2Fe(SO4)2.6H2O, is named Mohr's salt after him.

Life

Mohr was born in 1806 into the family of a prosperous druggist in Koblenz. The young Mohr received much of his early education at home, a great part of it in his father's laboratory. This experience may be responsible for much of the skill Mohr later showed in devising instruments and methods of chemical analysis. At the age of twenty-one he began to study chemistry under Leopold Gmelin, and, after five years in Heidelberg, Berlin and Bonn, he returned with the degree of PhD to join his father's establishment.{{sfn|Chisholm|1911}}

Mohr's father died during 1840 at which time Mohr assumed control of the family business. He retired from it for a life of scientific leisure in 1857, but at the age of fifty-seven some serious financial losses caused him to become a privatdozent in Bonn. In 1867 he was appointed, by the direct influence of the government, extraordinary professor of pharmacy.{{sfn|Chisholm|1911}}

Work

Mohr was the leading scientific chemist of his time in Germany, and the inventor of many improvements in analytical methodology. He invented an improved burette which had a tip at the bottom and a clamp (a 'Mohr's clip'), which made it much easier to use than its predecessors, which were more similar to a graduated cylinder. His methods of volumetric analysis were expounded in his Lehrbuch der chemisch-analytischen Titrir-methode (1855) (Instructional Book of Titration Methods in Analytical Chemistry), which won special commendation from Liebig and ran to many editions.[1] His Geschichte der Erde, eine Geologie auf neuer Grundlage (1866) (History of the Earth, a Geology on a New Basis), was also widely circulated.[2]{{sfn|Chisholm|1911}}

In a paper Über die Natur der Wärme (1837), Mohr gave one of the earliest general statements of the doctrine of the conservation of energy:[3]

{{quote|besides the 54 known chemical elements there is in the physical world one agent only, and this is called Kraft (energy). It may appear, according to circumstances, as motion, chemical affinity, cohesion, electricity, light and magnetism; and from any one of these forms it can be transformed into any of the others. {{sfn|Chisholm|1911}} }}

Selected writings

  • Commentar zur Preußischen Pharmacopoe nebst Übersetzung des Textes : nach der 6. Aufl. der Pharmacopoea Borussica bearbeitet ; für Apotheker, Aerzte und Medicinal-Beamte . Band 1 . Vieweg, Braunschweig 1848 Digital edition by the University and State Library Düsseldorf
  • Commentar zur Preußischen Pharmacopoe nebst Übersetzung des Textes : nach der 6. Aufl. der Pharmacopoea Borussica bearbeitet ; für Apotheker, Aerzte und Medicinal-Beamte . Band 2 . Vieweg, Braunschweig 1849 Digital edition by the University and State Library Düsseldorf
  • Commentar zur preussischen Pharmacopoe nebst Übersetzung des Textes : nach der sechsten Auflage der Pharmacopoea Borussica ; für Apotheker, Ärzte und Medicinal-Beamte Vol.1-2 . Vieweg, Braunschweig 2nd ed. 1854 Digital edition by the University and State Library Düsseldorf
  • Lehrbuch der chemisch-analytischen Titriermethode : für Chemiker, Ärzte u. Pharmaceuten, Berg- und Hüttenmänner, Fabrikanten, Agronomen, Metallurgen, Münzbeamte etc. ; nach eigenen Versuchen und systematisch dargestellt . Vieweg, Braunschweig 3. Aufl. 1870 Digital edition by the University and State Library Düsseldorf
  • {{cite book | author = Mohr, Friedrich | title = Lehrbuch der chemisch-analytischen Titrirmethode: Nach eigenen versuchen | year = 1877 | publisher = Freidrich Vieweg und Sohn | location = Braunschweig | url = https://books.google.com/?id=1xBDAAAAIAAJ&pg=PA80&dq=Lehrbuch+der+chemisch-analytischen+Titrir-methode}}

- Based on Mohr's work

References

1. ^{{cite book|last1=Mohr|first1=Karl Friedrich|title=Lehrbuch der chemisch-analytischen Titrirmethode … , part 1|date=1855|publisher=Friederich Vieweg und Sohn|location=Braunschweig, (Germany)|url=https://babel.hathitrust.org/cgi/pt?id=wu.89087461158;view=1up;seq=7|trans-title=Textbook of analytical chemistry titration methods … |language=German}} Page 3 shows Mohr's burette.
2. ^{{cite book|last1=Mohr|first1=Friedrich|title=Geschichte der Erde. Eine Geologie auf neuer Grundlage|trans-title=History of the Earth, a Geology on a New Basis|date=1866|publisher=Max Cohen & Sohn|location=Bonn, (Germany)|url=https://babel.hathitrust.org/cgi/pt?id=uc1.$b50628;view=1up;seq=5|language=German}}
3. ^Über die Natur der Wärme, Zeitschrift für Physik und verwandte Wissenschaften (Wien, 1937), Volume 5, pg 442. [https://books.google.com/books?id=wREPAQAAIAAJ&pg=PA442#v=onepage&q&f=false]
Attribution
  • {{Cite EB1911|wstitle=Mohr, Karl Friedrich}}

Further reading

{{Wikisource author}}{{Commons category|Karl Friedrich Mohr}}
  • {{cite journal | author = Oesper, Ralph E. | title = Karl Friedrich Mohr | journal = The Journal of Chemical Education | year = 1927 | volume = 4 | pages = 1357–1363 | doi = 10.1021/ed004p1357 | issue = 11 |bibcode = 1927JChEd...4.1357O }}
  • {{cite journal | author = Hofmann, Frederick | title = Sketch of Friedrich Mohr | journal = Popular Science Monthly |date=June 1880 | volume = 17 | pages = 402–404 | url = https://books.google.com/?id=W_QKAAAAYAAJ&pg=PA289-IA5&dq=Karl+Friedrich+Mohr | accessdate = 2008-02-09 | publisher = D. Appleton }}
  • Mohr, K. F. (1837) "Ansichten über die Natur der Wärme." Ann. der Pharm., 24, pp. 141–147.
  • Mohr, K. F. (1876) (trans. P. G. Tait) "Views of the nature of heat." Philosophical Magazine 2 110-14.
  • {{cite journal | author = Sella, Andrea | title = Mohr's Burette | journal = Chemistry World |date=March 2008 | pages = 81 | url = http://www.rsc.org/chemistryworld/Issues/2008/March/MohrsBurette.asp }}
  • See also this site for a different photograph of Mohr
{{EB1911|wstitle=Mohr, Karl Friedrich|volume=18|page=650}}{{Authority control}}{{DEFAULTSORT:Mohr, Karl Friedrich}}

7 : German chemists|1806 births|1879 deaths|People from Koblenz|German pharmacists|Scientific instrument makers|People from the Rhine Province

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