词条 | Manganese(II) nitrate |
释义 |
| Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 451483438 | Name = | ImageFile = Manganese(II) nitrate.svg | ImageSize = | ImageAlt = | ImageName = | ImageFile1 = Manganese nitrate tetrahydrate.jpg | ImageSize1 = | ImageAlt1 = | ImageName1 = Manganese(II) nitrate tetrahydrate | IUPACName = | PIN = | SystematicName = Manganese(II) nitrate | OtherNames = Manganese dinitrate |Section1={{Chembox Identifiers | Abbreviations = | CASNo = 10377-66-9 | CASNo_Ref = {{cascite|correct|CAS}} | CASNo1 = 20694-39-7 | CASNo1_Comment = (tetrahydrate) | CASNo1_Ref = {{cascite|correct|CAS}} | CASNo2_Ref = {{cascite|changed|??}} | CASNo2 = 17141-63-8 | CASNo2_Comment = (hexahydrate) | UNII_Ref = {{fdacite|changed|FDA}} | UNII = I389H78514 | PubChem = 61511 | PubChem_Comment = | ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}} | ChemSpiderID = 55431 | SMILES = [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Mn+2] | InChI = 1/Mn.2NO3/c;2*2-1(3)4/q+2;2*-1 | InChIKey = MIVBAHRSNUNMPP-UHFFFAOYAV | StdInChI_Ref = {{stdinchicite|changed|chemspider}} | StdInChI = 1S/Mn.2NO3/c;2*2-1(3)4/q+2;2*-1 | StdInChIKey_Ref = {{stdinchicite|changed|chemspider}} | StdInChIKey = MIVBAHRSNUNMPP-UHFFFAOYSA-N | EINECS = 233-828-8 | EC_number = | UNNumber = 2724 | DrugBank_Ref = {{drugbankcite|correct|drugbank}} | DrugBank = | KEGG_Ref = {{keggcite|correct|kegg}} | KEGG = | MeSHName = | ChEBI_Ref = {{ebicite|correct|EBI}} | ChEBI = | RTECS = | Beilstein = | Gmelin = | 3DMet = |Section2={{Chembox Properties | Formula = Mn(NO3)2 | MolarMass = 178.95 g/mol | Appearance = white powder | Density = 1.536 g/cm3 | MeltingPtC = 37 | MeltingPt_notes = | BoilingPtC = 100 | BoilingPt_notes = | Solubility = 118 g/100 ml(10oC) | LogP = | VaporPressure = | HenryConstant = | AtmosphericOHRateConstant = | pKa = | pKb = |Section3={{Chembox Structure | CrystalStruct = | Coordination = | MolShape = |Section4={{Chembox Thermochemistry | DeltaHf = | DeltaHc = | Entropy = | HeatCapacity = |Section7={{Chembox Hazards | ExternalSDS = | EUClass = | MainHazards = | NFPA-H = | NFPA-F = | NFPA-R = | NFPA-S = | RPhrases = | SPhrases = | RSPhrases = | FlashPt = | AutoignitionPt = | ExploLimits = | LD50 = | PEL = |Section8={{Chembox Related | OtherAnions = Manganese chloride | OtherCations = Magnesium nitrate Calcium nitrate | OtherFunction = | OtherFunction_label = | OtherCompounds = }}Manganese(II) nitrate are the inorganic compounds with formula Mn(NO3)2(H2O)n. Each formula unit is composed of one Mn2+ cation and two NO3− anions and varying amounts of water. Most common is the tetrahydrate Mn(NO3)2·4H2O, but mono- and hexahydrates are also known as well as the anhydrous compound. Some of these compounds are useful precursors to the oxides of manganese.[1] Preparation, reactions, usesManganese(II) nitrate is prepared by dissolving manganese(II) oxide in nitric acid: MnO + 2 HNO3 → Mn(NO3)2 + H2O It can also be prepared from manganese dioxide and nitrogen dioxide:[1] MnO2 + 2 NO2 → Mn(NO3)2 On heating to 300 °C, aqueous solutions of manganese(II) nitrate thermally decompose to form MnO2 and NO2. Manganese(II) nitrate is the precursor to manganese carbonate, which is used in fertilizers and as a colorant. The advantage of this method, use of ammonia and carbon dioxide, being that the side product ammonium nitrate is also useful as a fertilizer.[1] References1. ^1 2 Arno H. Reidies, "Manganese Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH, Weinheim. {{DOI|10.1002/14356007.a16_123}} {{Manganese compounds}}{{nitrates}}{{inorganic-compound-stub}} 2 : Manganese compounds|Nitrates |
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