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词条 Manganese(II) nitrate
释义

  1. Preparation, reactions, uses

  2. References

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| ImageFile = Manganese(II) nitrate.svg
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| ImageFile1 = Manganese nitrate tetrahydrate.jpg
| ImageSize1 =
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| ImageName1 = Manganese(II) nitrate tetrahydrate
| IUPACName =
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| SystematicName = Manganese(II) nitrate
| OtherNames = Manganese dinitrate
|Section1={{Chembox Identifiers
| Abbreviations =
| CASNo = 10377-66-9
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo1 = 20694-39-7
| CASNo1_Comment = (tetrahydrate)
| CASNo1_Ref = {{cascite|correct|CAS}}
| CASNo2_Ref = {{cascite|changed|??}}
| CASNo2 = 17141-63-8
| CASNo2_Comment = (hexahydrate)
| UNII_Ref = {{fdacite|changed|FDA}}
| UNII = I389H78514
| PubChem = 61511
| PubChem_Comment =
| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
| ChemSpiderID = 55431
| SMILES = [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Mn+2]
| InChI = 1/Mn.2NO3/c;2*2-1(3)4/q+2;2*-1
| InChIKey = MIVBAHRSNUNMPP-UHFFFAOYAV
| StdInChI_Ref = {{stdinchicite|changed|chemspider}}
| StdInChI = 1S/Mn.2NO3/c;2*2-1(3)4/q+2;2*-1
| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}
| StdInChIKey = MIVBAHRSNUNMPP-UHFFFAOYSA-N
| EINECS = 233-828-8
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| UNNumber = 2724
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|Section2={{Chembox Properties
| Formula = Mn(NO3)2
| MolarMass = 178.95 g/mol
| Appearance = white powder
| Density = 1.536 g/cm3
| MeltingPtC = 37
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| BoilingPtC = 100
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| Solubility = 118 g/100 ml(10oC)
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|Section8={{Chembox Related
| OtherAnions = Manganese chloride
| OtherCations = Magnesium nitrate
Calcium nitrate
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}}Manganese(II) nitrate are the inorganic compounds with formula Mn(NO3)2(H2O)n. Each formula unit is composed of one Mn2+ cation and two NO3 anions and varying amounts of water. Most common is the tetrahydrate Mn(NO3)2·4H2O, but mono- and hexahydrates are also known as well as the anhydrous compound. Some of these compounds are useful precursors to the oxides of manganese.[1]

Preparation, reactions, uses

Manganese(II) nitrate is prepared by dissolving manganese(II) oxide in nitric acid:

MnO + 2 HNO3 → Mn(NO3)2 + H2O

It can also be prepared from manganese dioxide and nitrogen dioxide:[1]

MnO2 + 2 NO2 → Mn(NO3)2

On heating to 300 °C, aqueous solutions of manganese(II) nitrate thermally decompose to form MnO2 and NO2.

Manganese(II) nitrate is the precursor to manganese carbonate, which is used in fertilizers and as a colorant. The advantage of this method, use of ammonia and carbon dioxide, being that the side product ammonium nitrate is also useful as a fertilizer.[1]

References

1. ^Arno H. Reidies, "Manganese Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH, Weinheim. {{DOI|10.1002/14356007.a16_123}}
{{Manganese compounds}}{{nitrates}}{{inorganic-compound-stub}}

2 : Manganese compounds|Nitrates

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