| 词条 | Methyl hypochlorite |
| 释义 |
| Verifiedfields = changed | verifiedrevid = 458444954 | ImageFile = Methyl hypochlorite.svg | ImageFileR1 = Methyl hypochlorite Space Fill 3D.png | ImageSizeR1 = 150px | ImageFileL1 = Methyl hypochlorite Ball and Stick 3D.png | ImageSizeL1 = 150px | PIN = (Chlorooxy)methane | SystematicName = Methyl hypochlorite | OtherNames = Hypochlorous acid methyl ester; Methoxy chloride |Section1={{Chembox Identifiers | CASNo_Ref = {{cascite|changed|??}} | CASNo = 593-78-2 | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/CH3ClO/c1-3-2/h1H3 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = UCFFGYASXIPWPD-UHFFFAOYSA-N | PubChem = 79056 | ChemSpiderID = 71388 | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | SMILES = COCl | InChI = 1S/CH3ClO/c1-3-2/h1H3 | InChIKey = UCFFGYASXIPWPD-UHFFFAOYSA-N}} |Section2={{Chembox Properties | C=1 | H=3 | Cl=1 | O=1 | Appearance = Gas | Odor = Pungent | Solubility = Decomposes | Solvent1 = Water | Solubility1 = | Solvent2 = | Solubility2 = | SolubleOther = | Density = 1.058 g/cm3 | MeltingPtC = -120.4 | BoilingPtC = 9.18 | RefractIndex = 1.343 | pKa = |Section3={{Chembox Structure | CrystalStruct = | SpaceGroup = | Coordination = | LattConst_a = |Section7={{Chembox Hazards | ExternalSDS = | NFPA-H = 4 | NFPA-F = | NFPA-R = 4 | FlashPt = | RPhrases = {{R3}} {{R8}} {{R23/24/25}} {{R35}} | SPhrases = | LD50 = }}Methyl hypochlorite is the simplest of the organic alkyl hypochlorites. It is an explosively unstable and highly toxic compound that can be produced by the reaction of methanol with hypochlorous acid.[1] It was first synthesized by Sandmeyer in the 1880s.[2] Methyl hypochlorite can form in the Earth's atmosphere by a reaction between ClO and CH3OO and is thought to be an important species in ozone destruction over the Arctic and Antarctic regions.[3] References1. ^{{cite journal |last1=Taylor |first1=M. C. |last2=MacMullin |first2=R. B. |last3=Gammal |first3=C. A. |title=HYPOCHLOROUS ACID AND THE ALKYL HYPOCHLORITES |journal=Journal of the American Chemical Society |date=February 1925 |volume=47 |issue=2 |pages=395–403 |doi=10.1021/ja01679a017}} {{Organic-compound-stub}}2. ^{{cite journal |last1=Sandmeyer |first1=Traugott |title=Ueber Aethyl- und Methylhypochlorit |journal=Berichte der deutschen chemischen Gesellschaft |date=January 1886 |volume=19 |issue=1 |pages=857–861 |doi=10.1002/cber.188601901196}} 3. ^{{cite journal |last1=Helleis |first1=Frank |last2=Crowley |first2=John |last3=Moortgat |first3=Geert |title=Temperature dependent CH3OCl formation in the reaction between CH3O2 and ClO |journal=Geophysical Research Letters |date=15 August 1994 |volume=21 |issue=17 |pages=1795–1798 |doi=10.1029/94GL01280}} 2 : Hypochlorites|Methyl esters |
| 随便看 |
|
开放百科全书收录14589846条英语、德语、日语等多语种百科知识，基本涵盖了大多数领域的百科知识，是一部内容自由、开放的电子版国际百科全书。