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词条 Nitronium tetrafluoroborate
释义

  1. Preparation

  2. Applications

  3. References

{{chembox
| verifiedrevid = 428761165
| ImageFile=Nitronium-tetrafluoroborate-xtal-CM-3D-ellipsoids-A.png
| ImageSize=
| ImageFile1=Nitronium-tetrafluoroborate-xtal-3D-SF.png
| OtherNames = nitronium fluoroborate, {{chem|NO|2|BF|4}}
|Section1={{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 13826-86-3
|Section2={{Chembox Properties
| Formula = BNO2F4
| MolarMass = 132.81
| MeltingPt =
| BoilingPt =
|Section3={{Chembox Hazards
| RPhrases = R34 R42 R43
| SPhrases = S26 S36 S37 S39 S45
| ExternalSDS =  
|Section8={{Chembox Related
| OtherCations = Nitrosonium tetrafluoroborate
}}

Nitronium tetrafluoroborate is an inorganic compound with formula NO2BF4. It is a salt of nitronium cation and tetrafluoroborate anion. It is a colorless crystalline solid, which reacts with water to form the corrosive acids HF and HNO3. As such, it must be handled under water-free conditions. It is sparsely soluble in many organic solvents.

Preparation

Nitronium tetrafluoroborate can be prepared by adding a mixture of anhydrous hydrogen fluoride and boron trifluoride to a nitromethane solution of nitric acid or dinitrogen pentoxide.[1]

Applications

Nitronium tetrafluoroborate is used as a nitration agent.

References

1. ^{{cite book| title = Aromatic nitration| author = Kenneth Schofield| publisher = CUP Archive| year = 1980| isbn = 0-521-23362-3| page = 88}}
{{tetrafluoroborates}}{{inorganic-compound-stub}}

2 : Tetrafluoroborates|Nitronium compounds

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