“Nitrosylation”的意思、由来-开放百科全书

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Nitrosylation

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Nitrosylation is the general term for covalent incorporation of a nitric oxide "nitrosyl" moiety into another (usually organic) molecule. There are multiple chemical mechanisms by which this can be achieved; including biological enzymes and industrial processes. The biological functions of nitrosylation are particularly important as S-nitrosylation, the conjugation of NO to cysteine thiols in proteins, is an important part of cell signalling.^[1]

Coordination of NO to transition metals to give metal nitrosyl complexes, is also referred to as nitrosylation.^[2]

References

1. ^{{cite journal |last1=Mannick |first1=Joan B. |last2=Schonhoff |first2=Christopher M. |title=Review: NO Means No and Yes: Regulation of Cell Signaling by Protein Nitrosylation |journal=Free Radical Research |date=7 July 2009 |volume=38 |issue=1 |pages=1–7 |doi=10.1080/10715760310001629065}}
2. ^{{cite journal|last=Hayton|first=T. W.|author2=Legzdins, P. |author3=Sharp, W. B. |year=2002|title=Coordination and Organometallic Chemistry of Metal-NO Complexes|journal=Chem. Rev.|volume=102|issue=1|pages=935–991|doi=10.1021/cr000074t|pmid=11942784}}

2 : Chemical reactions|Nitrogen cycle

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