请输入您要查询的百科知识:

 

词条 Ammonium iodide
释义

  1. Preparation

  2. References

{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 470456251
| Name = Ammonium iodide
| ImageFileL1 = Ammonium.svg
| ImageSizeL1 = 90px
| ImageNameL1 = The ammonium cation
| ImageFileR1 = I-.svg
| ImageSizeR1 = 20px
| ImageNameR1 = The iodide anion
| ImageFile2 = Ammonium-iodide-3D-balls.png
| ImageSize2 = 180px
| ImageName2 = ball-and-stick model of an ammonium cation (left) and an iodide anion (right)
| ImageName = Ammonium iodide
|Section1={{Chembox Identifiers
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = OZ8F027LDH
| InChI = 1/HI.H3N/h1H;1H3
| SMILES = [I-].[NH4+]
| InChIKey = UKFWSNCTAHXBQN-UHFFFAOYAU
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/HI.H3N/h1H;1H3
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = UKFWSNCTAHXBQN-UHFFFAOYSA-N
| CASNo = 12027-06-4
| CASNo_Ref = {{cascite|correct|CAS}}
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID =23785
| PubChem = 25487
|Section2={{Chembox Properties
| Formula = NH4I
| MolarMass = 144.94 g/mol
| Appearance = White crystalline powder
| Density = 2.51 g/cm3
| Solubility = 155 g/100 mL (0 °C)
172 g/100 mL (20 °C)
250 g/100 mL (100 °C)
| MeltingPtC = 551
| MeltingPt_notes = (sublimes)
| BoilingPtC = 235
| BoilingPt_notes = (in vacuum)
| MagSus = -66.0·10−6 cm3/mol
|Section7={{Chembox Hazards
| ExternalSDS =
| MainHazards =
| NFPA-H = 2
| NFPA-F = 0
| NFPA-R = 0
| FlashPt = Non-flammable
|Section8={{Chembox Related
| OtherAnions = Ammonium fluoride
Ammonium chloride
Ammonium bromide
| OtherCations = Sodium iodide
Potassium iodide
| OtherCompounds =
}}Ammonium iodide is the chemical compound NH4I. It is used in photographic chemicals and some medications.[1] It can be prepared by the action of hydroiodic acid on ammonia. It is easily soluble in water, from which it crystallizes in cubes. It is also soluble in ethanol. It gradually turns yellow on standing in moist air, owing to decomposition with liberation of iodine.[1]

Preparation

Ammonium iodide can be made in lab by reacting ammonia or ammonium hydroxide with hydroiodic acid or hydrogen iodide gas:

NH3 + HI → NH4I

NH4OH + HI → NH4I + H2O

It is also formed by the decomposition of ammoniated triiodoamine (an explosive).

References

1. ^Holleman, A. F.; Wiberg, E. Inorganic Chemistry Academic Press: San Diego, 2001. {{ISBN|0-12-352651-5}}.
{{inorganic-compound-stub}}

3 : Iodides|Nonmetal halides|Ammonium compounds

随便看

 

开放百科全书收录14589846条英语、德语、日语等多语种百科知识,基本涵盖了大多数领域的百科知识,是一部内容自由、开放的电子版国际百科全书。

 

Copyright © 2023 OENC.NET All Rights Reserved
京ICP备2021023879号 更新时间:2024/9/20 14:59:02