词条 | Organic nonlinear optical materials |
释义 |
Organic materials are expected to have relatively strong nonlinear optical properties due to delocalized electrons at * orbitals. This expectation explains extensive search for better NLO materials among organic crystals. L-arginine maleate dihydrate (LAMD)L-Arginine is one of the essential amino acids widely distributed in biological substances. It forms a number of salts with organic and inorganic acids showing non-linear optical properties. L-Arginine maleate dihydrate (LAMD, C6H14N4O2,C4H4O4,2H2O) is one of these L-arginine salts which is a complex of strongly basic amino acid, carboxylic acid and provides useful information in relation to molecular interaction in present-day biological systems and to prebiotic self-organisms.[1] It is also a nonlinear optical material with second harmonic generation efficiency 1.68 times that of KDP.[2] LAMD crystals are grown from solution by solvent evaporation; they belong to the triclinic space group P1. L-methionine L-methioninium hydrogen maleate (LMMM)LMMM too belongs to the amino acid family. Crystals are grown by slow evaporation of an aqueous solution containing L-methionine and maleic acid, resulting in centimeter-large crystals of a non-centrosymmetric space group.[3] They were applied for second harmonic generation of an YAG laser (wavelength 1064 nm), and SHG efficiency equal to that of KDP has been obtained. References1. ^S.L. Miller, E.L. Orgel, "The Origins of Life on the Earth", Prentice-Hall, New Jersey, 1974. 2. ^"Synthesis, crystal structure and solubility of C6H14N4O2,C4H4O4,2H2O" [https://dx.doi.org/10.1016/j.stam.2005.01.001 Sci. Technol. Adv. Mater. 6 (2005) 508] (free download) 3. ^"Crystal growth and structure of L-methionine L-methioninium hydrogen maleate—a new NLO material" [https://dx.doi.org/10.1088/1468-6996/9/2/025012 Sci. Technol. Adv. Mater. 9 (2008) 025012] (free download) 1 : Nonlinear optical materials |
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