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词条 Perfluorotripentylamine
释义

  1. Safety

  2. See also

  3. References

{{chembox
| verifiedrevid = 312624335
| ImageFile = Perfluorotripentylamine.svg
| ImageSize =
| ImageAlt =
| IUPACName = 1,1,2,2,3,3,4,4,5,5,5-Undecafluoro-N,N-bis(1,1,2,2,3,3,4,4,5,5,

5-undecafluoropentyl)pentan-1-amine


| OtherNames = Perfluorotriamylamine; Tri(perfluoropentyl)amine; Tris(perfluoropentyl)amine; Fluorinert FC-70; Perfluoro-compound FC-70; FC-70
|Section1={{Chembox Identifiers
| CASNo = 338-84-1
| CASNo_Ref = {{cascite|correct|}}
| PubChem = 67646
| ChemSpiderID = 60965
| SMILES = C(C(C(N(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(C(C(F)(F)F)(F)F)(F)F
| InChI = 1/C15F33N/c16-1(17,4(22,23)10(34,35)36)7(28,29)13(43,44)49(14(45,46)8(30,31)2(18,19)5(24,25)11(37,38)39)15(47,48)9(32,33)3(20,21)6(26,27)12(40,41)42
| InChIKey = AQZYBQIAUSKCCS-UHFFFAOYAN
| StdInChI = 1S/C15F33N/c16-1(17,4(22,23)10(34,35)36)7(28,29)13(43,44)49(14(45,46)8(30,31)2(18,19)5(24,25)11(37,38)39)15(47,48)9(32,33)3(20,21)6(26,27)12(40,41)42
| StdInChIKey = AQZYBQIAUSKCCS-UHFFFAOYSA-N}}
|Section2={{Chembox Properties
| C =15|F=33|N=1
| Appearance = Clear, colorless
| Density = 1940 kg/m3
| RefractIndex = 1.303
| MeltingPt =
| BoilingPtC = 215
| Solubility = <5 ppm
|Section3={{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt =
}}Perfluorotripentylamine is a perfluorocarbon. It is used as an electronics coolant, and has a high boiling point. It is colorless, odorless, and insoluble in water. Unlike ordinary amines, perfluoroamines are of low basicity. Perfluorinated amines are components of fluorofluids, used as immersive coolants for supercomputers.[1]

It is prepared by electrofluorination of the amine using hydrogen fluoride as solvent and source of fluorine:[1]

N(C5H11)3 + 33 HF → N(C5F11)3 + 33 H2

Safety

Fluoroamines are generally of very low toxicity, so much that they have been evaluated as synthetic blood.[1]

See also

  • Perfluorotributylamine

References

1. ^{{cite encyclopedia|title=Fluoroethers and Fluoroamines|authors=Michael G. Costello, Richard M. Flynn, John G. Owens|year=2001|publisher=Wiley-VCH|place=Weinstein|encyclopedia=Kirk-Othmer Encyclopedia of Chemical Technology|doi=10.1002/0471238961.0612211506122514.a01.pub2}}
Fluorinert FC-70 (3M){{fluorine compounds}}{{organohalide-stub}}

4 : Coolants|Halogenated solvents|Perfluorinated compounds|Amines

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