词条 | P. G. Owston |
释义 |
Owston's crystallography work included the determination of the structure of Zeise's salt,[5][6] the anion of which is shown at right. Zeise's salt, {{nowrap|K[PtCl3(η2-C2H4)]·H2O,}} was reported in 1831[7] and was one of the first organometallic compounds ever discovered. However, the nature of the platinum to ethylene bond in the compound was not understood until the development of the Dewar-Chatt-Duncanson model in the 1950s.[8][9][10] The space-filling model from the Owston crystal structure clearly shows that it is an organometallic species as there is direct bonding between the platinum metal centre (in blue) and the two carbon atoms of the ethylene ligand (in black). In 1964, Owston wrote an article in New Scientist[11] on the use of electron spin resonance spectroscopy in chemistry. References1. ^1 {{cite book|last = Ouston|first = Roger J.|title = A Directory of Ouston and Owston Families|publisher = Roger J. Ouston|year = 2003|chapter = Entries 1769-1771}} {{authority control}}{{DEFAULTSORT:Owston, Philip George}}{{UK-scientist-stub}}2. ^{{cite web|title = Place-Name Listing|publisher = United Kingdom Antarctic Place-Names Committee|url = http://www.add.scar.org:8080/geoserver/namelist.jsp|accessdate = January 9, 2011|deadurl = yes|archiveurl = https://web.archive.org/web/20080507193908/http://www.add.scar.org:8080/geoserver/namelist.jsp|archivedate = May 7, 2008|df = }} 3. ^1 {{cite web|url = http://www.geographic.org/geographic_names/antname.php?uni=11249&fid=antgeo_117|title = Owston Islands: Antarctica|author = National Geospatial-Intelligence Agency|publisher = Geographical Names (geographic.org)|accessdate = January 9, 2011}} 4. ^{{cite book|last = Beck|first = Peter J.|title = The International Politics of Antarctica|publisher = Routledge|year = 1986|pages = 119–120|url = https://books.google.com/books?hl=en&lr=&id=-4g9AAAAIAAJ&oi=fnd&pg=PP15|isbn = 978-0-7099-3239-0}} 5. ^1 {{cite journal|title = The crystal and molecular structure of Zeise's salt, KPtCl3.C2H4.H2O|last1 = Black|first1 = M|last2 = Mais|first2 = R. H. B.|last3 = Owston|first3 = P. G.|authorlink3 = P. G. Owston|year = 1969|journal = Acta Crystallogr. B|volume = 25|issue = 9|pages = 1753–1759|doi = 10.1107/S0567740869004699}} 6. ^1 {{cite journal|title = A Re-determination of the Crystal and Molecular Structure of Zeise's salt, KPtCl3.C2H4.H2O|last1 = Jarvis|first1 = J. A. J.|last2 = Kilbourn|first2 = B. T.|last3 = Owston|first3 = P. G.|authorlink3 = P. G. Owston|journal = Acta Crystallogr. B|volume = 27|issue = 2|year = 1971|pages = 366–372|doi = 10.1107/S0567740871002231}} 7. ^{{cite journal|last = Zeise|first = W. C.|authorlink = William Christopher Zeise|title = Von der Wirkung zwischen Platinchlorid und Alkohol, und von den dabei entstehenden neuen Substanzen|journal = Annalen der Physik|volume = 97|issue = 4|pages = 497–541|year = 1831|doi = 10.1002/andp.18310970402|bibcode = 1831AnP....97..497Z|language = German}} 8. ^{{cite journal|title = A Historical Perspective on Dewar's Landmark Contribution to Organometallic Chemistry|last = Mingos|first = D. Michael P.|authorlink = Michael Mingos|journal = J. Organomet. Chem.|volume = 635|issue = 1–2|pages = 1–8|doi = 10.1016/S0022-328X(01)01155-X}} 9. ^{{cite book|title = Modern Coordination Chemistry: The Legacy of Joseph Chatt|editor1-last = Leigh|editor1-first = G. J.|editor2-last = Winterton|editor2-first = N.|year = 2002|publisher = RSC Publishing|chapter = Some Notes on the Early Development of Models of Bonding in Olefin-Metal Complexes|last = Winterton|first = N.|pages = 103–110|isbn = 978-0-85404-469-6|url = https://books.google.com/books?id=VoBxtPb5zCcC&pg=PA103}} 10. ^{{cite book|title = Organometallic Chemistry and Catalysis|last = Astruc|first = Didier|authorlink = Didier Astruc|year = 2007|publisher = Springer|pages = 41–43|isbn = 978-3-540-46128-9|url = https://books.google.com/books?id=aVyfo52-nRsC&pg=PA41}} 11. ^{{cite journal|title = Electron Spin Resonance|volume = 24|issue = 416|date = November 5, 1964|pages = 373–377|journal = New Scientist|last = Owston|first = P. G.|authorlink = P. G. Owston|url = https://books.google.com/books?id=lA9dMmYkYIsC&pg=PA392}} 4 : British chemists|1921 births|2001 deaths|People from North Yorkshire |
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