| 词条 | Plumbocene |
| 释义 |
| Watchedfields = changed | verifiedrevid = 444766390 | ImageFile = Plumbocene.svg | ImageSize = 80px | ImageAlt = | IUPACName = | PIN = | OtherNames = |Section1={{Chembox Identifiers | CASNo_Ref = {{cascite|correct|??}} | CASNo = 1294-74-2 | PubChem = | SMILES = }} |Section2={{Chembox Properties | C=10 | H=10 | Pb=1 | Appearance = | Density = | MeltingPt = | BoilingPtC = 150 | BoilingPt_notes = at 10−7 mmHg[1] | Solubility = |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }}Plumbocene is an organometallic compound of lead. It is a member of the class of metallocenes. It is soluble in benzene, acetone, ether, and petroleum ether, and insoluble in water. Plumbocene is stable in cold water.[1] Plumbocene is not commercially available. It may be synthesized by the reaction of sodium cyclopentadienide with a lead(II) source such as lead(II) nitrate[1] or lead(II) iodide.[2] The decamethyl analog, Cp*2Pb, and the half-sandwich complexes, Cp*PbBF4 and Cp*PbCl, are known as well.[3] References1. ^1 2 {{cite journal | last1 = Fischer | first1 = E. O. | authorlink = Ernst Otto Fischer | last2 = Grubert | first2 = H. | title = Über Aromatenkomplexe von Metallen. IV. Di-cyclopentadienyl-blei | journal = Zeitschrift für anorganische und allgemeine Chemie | volume = 286 | pages = 237 | year = 1956 | doi = 10.1002/zaac.19562860507 | issue = 5–6 }} {{Lead compounds}}2. ^{{cite journal | last1 = Izod | first1 = Keith | last2 = McFarlane | first2 = William | last3 = Wills | first3 = Corinne | last4 = Clegg | first4 = William | last5 = Harrington | first5 = Ross W. | title = Agostic-Type…Pb Interactions Stabilize a Dialkylplumbylene. Structure of and Bonding in [{nPr2P(BH3)}(Me3Si)C(CH2)]2Pb | journal = Organometallics | volume = 27 | pages = 4386 | year = 2008 | doi = 10.1021/om800598b}} 3. ^{{cite journal | last1 = Jutzi | first1 = Peter | last2 = Dickbreder | first2 = Reiner | last3 = Nöth | first3 = Heinrich | title = Blei(II)-Verbindungen mit π-gebundenen Pentamethylcyclopentadienylliganden – Synthesen, Strukturen und Bindungsverhältnisse | journal = Chemische Berichte | volume = 122 | pages = 865 | year = 1989 | doi = 10.1002/cber.19891220512 | issue = 5}} 3 : Metallocenes|Lead compounds|Cyclopentadienyl complexes |
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