词条 | Tetraphenylethylene |
释义 |
| Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 420384835 | ImageFile = Tetraphenylethylene.svg | ImageSize = | ImageAlt = | IUPACName = 1,2,2-triphenylvinylbenzene | OtherNames = tetraphenylethylene, tetraphenylethene, 1,1,2,2-tetraphenylethylene, 1,1,2,2-tetraphenylethene, tetraphenyl ethylene |Section1={{Chembox Identifiers | CASNo_Ref = {{cascite|correct|??}} | CASNo = 632-51-9 | PubChem =69437 | Beilstein = 789087 | ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}} | ChemSpiderID = 62645 | InChI = 1/C26H20/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22)26(23-17-9-3-10-18-23)24-19-11-4-12-20-24/h1-20H | InChIKey = JLZUZNKTTIRERF-UHFFFAOYAF | StdInChI_Ref = {{stdinchicite|changed|chemspider}} | StdInChI = 1S/C26H20/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22)26(23-17-9-3-10-18-23)24-19-11-4-12-20-24/h1-20H | StdInChIKey_Ref = {{stdinchicite|changed|chemspider}} | StdInChIKey = JLZUZNKTTIRERF-UHFFFAOYSA-N | SMILES = c1ccc(cc1)C(=C(c2ccccc2)c3ccccc3)c4ccccc4 }} |Section2={{Chembox Properties | C=26 | H=20 | MolarMass = | Appearance = white to light yellow to light beige crystalline powder | Density = 1.088 g/cm3 | MeltingPtC = 224 to 225 | MeltingPt_ref = [1] | BoilingPtC = 424 | BoilingPt_ref = [2] | Solubility = |Section3={{Chembox Hazards | MainHazards = | FlashPtC = 206.2 | AutoignitionPtC = }} Tetraphenylethylene is a chemical compound that can be used in construction{{clarify|construction of what?|date=March 2011}} and in the manufacture of medical equipment,{{Dubious|date=March 2011}} packaging, and electrical appliances.{{Citation needed|date=March 2011}} SynthesisTetraphenylethylene can be synthesized from diphenyldichloromethane.[3] References1. ^{{cite journal|last=Banerjee|first=Moloy|author2=Susanna J. Emond |author3=Sergey V. Lindeman |author4=Rajendra Rathore|authorlink4=Rajendra Rathore (chemist) |year=2007|title=Practical Synthesis of Unsymmetrical Tetraarylethylenes and Their Application for the Preparation of [Triphenylethylene−Spacer−Triphenylethylene] Triads|journal=The Journal of Organic Chemistry|volume=72|issue=21|pages=8054–8061|issn=0022-3263|doi=10.1021/jo701474y}} {{hydrocarbon-stub}}2. ^{{cite journal|last=Lewis|first=Irwin C.|author2=T. Edstrom |year=1963|title=Thermal Reactivity of Polynuclear Aromatic Hydrocarbons|journal=The Journal of Organic Chemistry|volume=28|issue=8|pages=2050–2057|issn=0022-3263|doi=10.1021/jo01043a025}} 3. ^{{cite journal|last=Inaba|first=S|year=1982|title=Metallic nickel as a reagent for the coupling of aromatic and benzylic halides|journal=Tetrahedron Letters|volume=23|issue=41|pages=4215–4216|issn=0040-4039|doi=10.1016/S0040-4039(00)88707-9}} 1 : Aromatic hydrocarbons |
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