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词条 2,4-Dihydroxy-1,4-benzoxazin-3-one-glucoside dioxygenase
释义

  1. References

  2. External links

{{Infobox enzyme
| Name = 2,4-dihydroxy-1,4-benzoxazin-3-one-glucoside dioxygenase
| EC_number = 1.14.20.2
| CAS_number =
| IUBMB_EC_number = 1/14/20/2
| GO_code =
| image =
| width =
| caption =
}}2,4-dihydroxy-1,4-benzoxazin-3-one-glucoside dioxygenase ({{EC number|1.14.20.2}}, BX6 (gene), DIBOA-Glc dioxygenase) is an enzyme with systematic name (2R)-4-hydroxy-3-oxo-3,4-dihydro-2H-1,4-benzoxazin-2-yl beta-D-glucopyranoside:oxygen oxidoreductase (7-hydroxylating).[1] This enzyme catalyses the following chemical reaction

(2R)-4-hydroxy-3-oxo-3,4-dihydro-2H-1,4-benzoxazin-2-yl beta-D-glucopyranoside + 2-oxoglutarate + O2 (2R)-4,7-dihydroxy-3-oxo-3,4-dihydro-2H-1,4-benzoxazin-2-yl beta-D-glucopyranoside + succinate + CO2 + H2O

The enzyme is involved in the biosynthesis of protective and allelopathic benzoxazinoids in some plants.

References

1. ^{{cite journal | vauthors = Jonczyk R, Schmidt H, Osterrieder A, Fiesselmann A, Schullehner K, Haslbeck M, Sicker D, Hofmann D, Yalpani N, Simmons C, Frey M, Gierl A | title = Elucidation of the final reactions of DIMBOA-glucoside biosynthesis in maize: characterization of Bx6 and Bx7 | journal = Plant Physiology | volume = 146 | issue = 3 | pages = 1053–63 | date = March 2008 | pmid = 18192444 | pmc = 2259038 | doi = 10.1104/pp.107.111237 }}

External links

  • {{MeshName|2,4-dihydroxy-1,4-benzoxazin-3-one-glucoside+dioxygenase}}
{{Dioxygenases}}{{Enzymes}}{{Portal bar|Molecular and Cellular Biology|border=no}}

1 : EC 1.14.20

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