| 词条 | 2-Methoxypropene |
| 释义 |
| ImageFileL1 = 2-Methoxypropene skeletal.svg | ImageSizeL1 = 80px | ImageFileR1 = 2-Methoxypropene.svg | ImageSizeR1 = 120px | IUPACName = 2-Methoxy-1-propene | OtherNames = 2-Methoxyprop-1-ene; Methyl isopropenyl ether; Isopropenyl methyl ether |Section1={{Chembox Identifiers | CASNo = 116-11-0 | CASNo_Ref = {{cascite|correct|CAS}} | PubChem = 8300 | ChemSpiderID = 7999 | SMILES = CC(=C)OC | InChI = 1/C4H8O/c1-4(2)5-3/h1H2,2-3H3 | InChIKey = YOWQWFMSQCOSBA-UHFFFAOYAD | StdInChI = 1S/C4H8O/c1-4(2)5-3/h1H2,2-3H3 | StdInChIKey = YOWQWFMSQCOSBA-UHFFFAOYSA-N |Section2={{Chembox Properties | C=4 | H=8 | O=1 | Appearance = Colorless liquid[1] | Density = 0.753 g/mL[2] | MeltingPt = | BoilingPtC = 34 to 36 | BoilingPt_ref = [2] | Solubility = |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }}2-Methoxypropene is an ether with the chemical formula C4H8O. It is a reagent used in organic synthesis as a protecting group for alcohols,[1] and the conversion diols to the acetonide group.[3] 2-Methoxypropene can be prepared by the elimination of methanol from dimethoxypropane,[4] or by the addition of methanol to propyne or allene.[5] References1. ^1 {{cite book | doi = 10.1002/047084289X.rm124 | chapter = 2-Methoxypropene | title = Encyclopedia of Reagents for Organic Synthesis | year = 2001 | last1 = Whitaker | first1 = K. Sinclair | last2 = Whitaker | first2 = D. Todd | isbn = 0471936235}} {{DEFAULTSORT:Methoxypropene, 2-}}2. ^1 2-Methoxypropene at Sigma-Aldrich 3. ^{{cite book | title = Protective Groups in Organic Synthesis | author1 = Theodora W. Greene | author2 = Peter G. M. Wuts | edition = 3rd | pages = 207–215}} 4. ^{{cite journal | doi = 10.1021/jo00956a040 | title = Improved synthesis of 2-methoxypropene | year = 1973 | last1 = Newman | first1 = Melvin S. | last2 = Vander Zwan | first2 = Michael C. | journal = The Journal of Organic Chemistry | volume = 38 | issue = 16 | pages = 2910}} 5. ^{{cite journal | doi = 10.1007/BF00765172 | title = Kinetics of the catalytic synthesis of 2-methoxypropene | year = 1983 | last1 = Agré | first1 = B. A. | last2 = Taber | first2 = A. M. | last3 = Beregovykh | first3 = V. V. | last4 = Klebanova | first4 = F. D. | last5 = Nekrasov | first5 = N. V. | last6 = Sobolev | first6 = O. B. | last7 = Kalechits | first7 = I. V. | journal = Pharmaceutical Chemistry Journal | volume = 17 | issue = 3 | pages = 221}} 2 : Reagents for organic chemistry|Ethers |
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