| 词条 | 3,4-Epoxycyclohexanecarboxylate methyl ester |
| 释义 |
| ImageFile = 3,4-Epoxycyclohexancarboxylatmethylester.svg | ImageSize = 200px | ImageAlt = | IUPACName = | OtherNames = |Section1={{Chembox Identifiers | CASNo = 41088-52-2 | PubChem = 12770164 | SMILES = COC(=O)C1CCC2C(C1)O2 | ChemSpiderID = 11227215 | StdInChI = 1S/C8H12O3/c1-10-8(9)5-2-3-6-7(4-5)11-6/h5-7H,2-4H2,1H3 | StdInChIKey = QCGKUFZYSPBMAY-UHFFFAOYSA-N |Section2={{Chembox Properties | C=8 | H=12 | O=3 | Appearance = Colorless liquid[1] | Density = | MeltingPt = | BoilingPtC = 109.5–110.5 | BoilingPt_notes = (17 mmHg) | BoilingPt_ref = [2] | Solubility = |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }} 3,4-Epoxycyclohexanecarboxylate methyl ester is a cycloaliphatic epoxide, which is added as monovalent monomer to other monomers for the production of crosslinked epoxy resins.[3][3] 3,4-Epoxycyclohexanecarboxylate methyl ester itself would give a linear polymer when homopolymerized. Production3,4-Epoxycyclohexanecarboxylate methyl ester is prepared by epoxidation of 4-cyclohexenecarboxylate methyl ester with peracid.[4] Properties3,4-Epoxycyclohexanecarboxylate methyl ester has a viscosity of 6 mPa·s.[4] References1. ^{{cite journal|author =James V. Crivello, Ulrike Varlemann |title= Mechanistic study of the reactivity of 3,4-epoxycyclohexylmethyl 3′,4′-epoxycyclohexancarboxylate in photoinitiated cationic polymerizations|journal=Journal of Polymer Science Part A: Polymer Chemistry |date=October 1995|volume=33 |issue=14|pages=2473–2486 |doi=10.1002/pola.1995.080331421}} {{DEFAULTSORT:Epoxycyclohexanecarboxylate methyl ester, 3,4-}}2. ^{{cite journal| author=NORMAN A. NELSON , GEORGE A. MORTIMER |title=Bicyclo[3.1.0]hexane Derivatives. I. Synthesis of Bicyclo[3.1.0]-2-hexanone and Methyl Bicyclo[3.1.0]hexane-1-carboxylate|journal=The Journal of Organic Chemistry|date=October 1957|volume=22|issue=10|pages=1146–1153|doi=10.1021/jo01361a003}} 3. ^{{patent|US|6201070|"METHOD FOR ENHANCING THE TOUGHNESS OF CYCLOALIPHATIC EPOXIDE-BASED COATINGS."|Naofumi Kumabe filing date 2001-03-13}} 4. ^1 2 {{cite journal|last1=Pham|first1=Ha Q.|last2=Marks|first2=Maurice J.|title=Epoxy Resins|journal=Ullmann's Encyclopedia of Industrial Chemistry|doi=10.1002/14356007.a09_547.pub2}} 4 : Carboxylate esters|Cyclohexanes|Epoxides|Methyl esters |
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