| 词条 | 3-Bromothiophene |
| 释义 |
| ImageFile = 3-Bromothiophene.svg | ImageSize = 100px | PIN = 3-Bromothiophene | OtherNames = 3-Thienyl bromide, 3BT | Section1 = {{Chembox Identifiers | CASNo = 872-31-1 | EINECS = 212-821-3 | SMILES = C1=CSC=C1Br | PubChem = 13383 | ChemSpiderID = 12811 | UNII = G818Z74YV0 | InChI = 1/C4H3BrS/c5-4-1-2-6-3-4/h1-3H | InChIKey = XCMISAPCWHTVNG-UHFFFAOYAH | StdInChI = 1S/C4H3BrS/c5-4-1-2-6-3-4/h1-3H | StdInChIKey = XCMISAPCWHTVNG-UHFFFAOYSA-N}} | Section2 = {{Chembox Properties | C=4|H=3|Br=1|S=1 | Appearance = Colorless liquid | Density = 1.74 g/mL | MeltingPtC = -10 | BoilingPtC = 150-158 | Solubility = Immiscible }} | Section3 = {{Chembox Hazards | GHSPictograms = {{GHS02}}{{GHS06}}{{GHS07}}{{GHS09}} | GHSSignalWord = Danger | HPhrases = {{H-phrases|226|301|310|310|315|317|319|330|335|411}} | PPhrases = {{P-phrases|210|233|240|241|242|243|260|261|262|264|270|271|272|273|280|284|301+310|302+350|302+352|303+361+353|304+340|305+351+338|310|312|320|321|322|330|332+313|333+313|337+313|361|362|363|370+378|391|403+233|403+235|405|501}} | MainHazards = N,Xi,Xn,T | FlashPtC = 56}} }}3-Bromothiophene is an organosulfur compound with the formula C4H3BrS. It is a colorless liquid. It is a precursor to the antibiotic timentin and the vasodialator Cetiedil.[1] PreparationUnlike 2-bromothiophene, the 3-bromo isomer cannot be prepared directly from thiophene. It can be prepared by debromination of 2,3,5-tribromothiophene:[2] The tribromothiophene is obtained by bromination of thiophene. {{clear|left}}See also
References1. ^{{Ullmann|author=Jonathan Swanston|title=Thiophene|year=2006|doi=10.1002/14356007.a26_793.pub2}} {{DEFAULTSORT:Bromothiophene, 3-}}{{organohalide-stub}}2. ^{{cite journal|author=S. Gronowitz|year=1959|doi=10.15227/orgsyn.044.0009|title=3-Bromothiophene|journal=Org. Syntheses|volume=44|pages=9}} 2 : Thiophenes|Bromoarenes |
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