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词条 Octafluoropropane
释义

  1. Applications

  2. Liquid phase

  3. Gaseous phase

  4. Major hazards

  5. References

  6. External links

{{chembox
| Verifiedimages = changed
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 411560223
| Name = Octafluoropropane
| ImageFile_Ref = {{chemboximage|correct|??}}
| ImageFileL1 = Octafluoropropane.png
| ImageSizeL1 = 130
| ImageAltL1 = Structural formula of octafluoropropane
| ImageFileR1 = Octafluoropropane 3D ball.png
| ImageSizeR1 = 135
| ImageAltR1 = Ball-and-stick model of octafluoropropane
| IUPACName = Octafluoropropane
| OtherNames = Freon 218
Perfluoropropane
RC 218, PFC 218
R218
Flutec PP30
genetron 218
|Section1={{Chembox Identifiers
| DrugBank_Ref = {{drugbankcite|changed|drugbank}}
| DrugBank = DB00556
| ChEBI_Ref = {{ebicite|changed|EBI}}
| ChEBI = 31980
| SMILES = FC(F)(F)C(F)(F)C(F)(F)F
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 6192
| PubChem = 6432
| ChEMBL_Ref = {{ebicite|correct|EBI}}
| ChEMBL = 1663
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = CK0N3WH0SR
| KEGG_Ref = {{keggcite|correct|kegg}}
| KEGG = D01738
| InChI = 1/C3F8/c4-1(5,2(6,7)8)3(9,10)11
| InChIKey = QYSGYZVSCZSLHT-UHFFFAOYAL
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/C3F8/c4-1(5,2(6,7)8)3(9,10)11
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = QYSGYZVSCZSLHT-UHFFFAOYSA-N
| CASNo = 76-19-7
| CASNo_Ref = {{cascite|correct|CAS}}
| RTECS = TZ5255000
|Section2={{Chembox Properties
| Formula = C3F8
| MolarMass = 188.02 g/mol
| Appearance = Colorless gas with
faintly sweet odor
| Density = 8.17 g/l, gas
| Solubility =
| MeltingPtC = -183
| MeltingPt_notes =
| BoilingPtC = -36.7
| BoilingPt_notes =
|Section3={{Chembox Structure
| Dipole = 0.014 D
|Section7={{Chembox Hazards
| ExternalSDS =
| MainHazards = Suffocation
| NFPA-H = 1
| NFPA-F = 0
| NFPA-R = 0
| FlashPt = N/A
| RSPhrases = R: ?
S: ?
|Section8={{Chembox Related
| OtherFunction_label = halocarbons
| OtherFunction = Tetrafluoromethane
Hexafluoroethane
| OtherCompounds = Propane
}}Octafluoropropane (C3F8) is a fluorocarbon non-flammable greenhouse gas that can be produced either by electrochemical fluorination or by the Fowler process using cobalt fluoride.[1]

Applications

In the electronics industry, octafluoropropane is mixed with oxygen and used as a plasma etching material for SiO2 layers in semiconductor applications, as oxides are selectively etched versus their metal substrates.[2]

In medicine, octafluoropropane may compose the gas cores of microbubble contrast agents used in contrast-enhanced ultrasound. Octafluoropropane microbubbles reflect sound waves well and are used to improve the ultrasound signal backscatter.

It is used in eye surgery, such as pars plana vitrectomy procedures where a retina hole or tear is repaired. The gas provides a long-term tamponade, or plug, of a retinal hole or tear and allows re-attachment of the retina to occur over the several days following the procedure.

Under the name R-218, octafluoropropane is used in other industries as a component of refrigeration mixtures.

It has been featured in some plans for terraforming Mars. With a greenhouse gas effect 24,000 times greater than CO2, octafluoropropane could dramatically reduce the time and resources it takes to terraform Mars.[3]

It is the active liquid in PICO-2L dark matter bubble detector (joined PICASSO and COUPP collaborations).

Liquid phase

  • Liquid density (1.013 bar at boiling point) : 1601 kg/m3
  • Liquid/gas equivalent (1.013 bar and 15 °C (59 °F)) : 196 vol/vol
  • Latent heat of vaporization (1.013 bar at boiling point) : 104.25 kJ/kg[4]

Gaseous phase

  • Gas density (1.013 bar at boiling point) : 10.3 kg/m3
  • Gas density (1.013 bar and 15 °C (59 °F)) : 8.17 kg/m3
  • Compressibility Factor (Z) (1.013 bar and 15 °C (59 °F)) : 0.975
  • Specific gravity (air = 1) (1.013 bar and 21 °C (70 °F)) : 6.683
  • Specific volume (1.013 bar and 21 °C (70 °F)) : 0.125 m3/kg
  • Viscosity (1.013 bar and 0 °C (32 °F)) : 0.000125 Poise
  • Thermal conductivity (1.013 bar and 0 °C (32 °F)) : 12.728 mW/(m·K)
  • Thermal Conductivity, Gas @ 101.325 kPa and 25 °C: 13.8 mW/(m·K)
  • Vapour Pressure @ 21.1 °C: 792 kPa[4]

Major hazards

  • Greenhouse gas
  • Inert gas asphyxiation

References

1. ^{{cite journal | title = Synthesis of Fluorocarbons| vauthors = Fowler RD, Buford III WB, Hamilton Jr JM, Sweet RG, Weber CE, Kasper JS, Litant I| journal = Ind. Eng. Chem.| year = 1947| volume = 39| issue =3| pages = 292–298| doi = 10.1021/ie50447a612 }}
2. ^{{cite journal| title = Plasma-assisted etching| journal = Plasma Chemistry and Plasma Processing| volume = 2| issue = 1 | year = 1982| doi =10.1007/BF00566856| pages = 1–41| author = Coburn, J. W.}}
3. ^{{cite conference| author =D. Rogers| coauthors =| date =17–21 October 2005| title =Studies in the Future of Experimental Terraforming| conference =56th International Astronautical Congress of the International Astronautical Federation| conferenceurl =| booktitle =| editor =| others =| volume =| edition =| publisher =International Academy of Astronautics, and the International Institute of Space Law| location =Fukuoka, Japan| pages =| url =http://pdf.aiaa.org/preview/CDReadyMIAF05_1429/PVIAC-05-D4.1.06.pdf| format =| accessdate =| doi =| id =| oclc =}}{{dead link|date=February 2018 |bot=InternetArchiveBot |fix-attempted=yes }}
4. ^{{cite web| url = http://encyclopedia.airliquide.com/encyclopedia.asp?GasID=47&CountryID=19&LanguageID=2| title =Encyclopédie des gaz| publisher = air liquide}}

External links

  • Red Planet Turning Green?
  • [https://web.archive.org/web/20050421015312/http://properties.nist.gov/fluidsci/data/r218da.htm Compressed Liquid Densities for octafluoropropane R218]

2 : Fluorocarbons|Refrigerants

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