词条 | 7-Deoxyloganetic acid |
释义 |
| ImageFile = 7-Deoxyloganetic acid.svg | ImageSize = 150px | IUPACName = (1R,4aS,7S,7aR)-1-Hydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-4-carboxylic acid | OtherNames = |Section1={{Chembox Identifiers | CASNo = | PubChem = 25203532 | ChemSpiderID = 30786131 | ChEBI = 76846 | SMILES = C[C@H]1CC[C@H]2[C@@H]1[C@@H](OC=C2C(=O)O)O | InChI = 1/C10H14O4/c1-5-2-3-6-7(9(11)12)4-14-10(13)8(5)6/h4-6,8,10,13H,2-3H2,1H3,(H,11,12)/t5-,6+,8+,10+/m0/s1 | InChIKey = DKGYTSKPMLWLEI-FIZOKRMRBX | StdInChI = 1S/C10H14O4/c1-5-2-3-6-7(9(11)12)4-14-10(13)8(5)6/h4-6,8,10,13H,2-3H2,1H3,(H,11,12)/t5-,6+,8+,10+/m0/s1 | StdInChIKey = DKGYTSKPMLWLEI-FIZOKRMRSA-N |Section2={{Chembox Properties | C=10 | H=14 | O=4 | Appearance = | Density = | MeltingPt = | BoilingPt = | Solubility = |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }}7-Deoxyloganetic acid is an iridoid monoterpene. It is produced from nepetalactol or iridodial by the enzyme iridoid oxidase (IO).[1] 7-Deoxyloganetic acid is a substrate for 7-deoxyloganetic acid glucosyltransferase (7-DLGT) which synthesizes 7-deoxyloganic acid.[2] References1. ^Miettinen, Dong, Navrot, Schneider, Burlat, et al. (2014) The seco-iridoid pathway from Catharanthus roseus. Nat Commun. 5 {{DEFAULTSORT:Deoxyloganetic acid, 7-}}{{organic-compound-stub}}2. ^Salim, Wiens, Masada-Atsumi, Yu and De Luca (2014) 7-Deoxyloganetic acid synthase catalyzes a key 3 step oxidation to form 7-deoxyloganetic acid in Catharanthus roseus iridoid biosynthesis. Phytochemistry. 101(0). 23-31 3 : Iridoids|Carboxylic acids|Cyclopentanes |
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