| 词条 | Adams decarboxylation |
| 释义 |
The Adams decarboxylation is a chemical reaction that involved the decarboxylation of coumarins which have carboxylic acid group in the third position. The decarboxylation is achieved by aqueous solution of sodium bisulfite, heat and a concentrated solution of sodium hydroxide.[1][2][3] References1. ^{{cite journal|author1=Adams, R. |author2=Mathieu, J. |journal= J. Am. Chem. Soc.|year=1948|volume=70|pages=2120|doi=10.1021/ja01186a037|title=A New Synthesis of Atranol (2,6-Dihydroxy-4-methylbenzaldehyde) and the Corresponding Cinnamic Acid|issue=6}} 2. ^{{cite journal|author1=Adams, R. |author2=Bockstaheler, T.E. |journal=J. Am. Chem. Soc.|year=1952|volume=74|pages=5346|doi=10.1021/ja01141a038|title=Preparation and Reactions of o-Hydroxycinnamic Acids and Esters|issue=21}} 3. ^{{cite journal|author1=Cramer, F. |author2=Windel, H. |journal= Chem. Ber. |year=1956|volume=89|pages=354|doi=10.1002/cber.19560890227|title=Über Einschlußverbindungen, X. Mitteil.: Die blauen Jodverbindungen der Cumarine und anderer verwandter Verbindungen|issue=2}} 2 : Organic reactions|Name reactions |
| 随便看 |
|
开放百科全书收录14589846条英语、德语、日语等多语种百科知识，基本涵盖了大多数领域的百科知识，是一部内容自由、开放的电子版国际百科全书。