| 词条 | Ammonium perfluorononanoate |
| 释义 |
| ImageFile =Ammonium perfluorononanoate.svg | ImageSize = 200px | IUPACName = Heptadecafluorononanoic acid ammoniate (1:1) | OtherNames = |Section1={{Chembox Identifiers | CASNo = 4149-60-4 | PubChem = 160734 | ChemSpiderID = 69647 | SMILES = FC(F)(C(F)(F)C(=O)O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F.N | InChI = 1/C9HF17O2.H3N/c10-2(11,1(27)28)3(12,13)4(14,15)5(16,17)6(18,19)7(20,21)8(22,23)9(24,25)26;/h(H,27,28);1H3 | InChIKey = ORBBVPFDROYXQS-UHFFFAOYAU | StdInChI = 1S/C9HF17O2.H3N/c10-2(11,1(27)28)3(12,13)4(14,15)5(16,17)6(18,19)7(20,21)8(22,23)9(24,25)26;/h(H,27,28);1H3 | StdInChIKey = ORBBVPFDROYXQS-UHFFFAOYSA-N |Section2={{Chembox Properties | Formula = C9H4F17NO2 | MolarMass = 481.106 | Appearance = | MeltingPt = | Density = 1.753 g/mL | BoilingPtC = 196 | Solubility = | CMC = ~8.0 mmol/L[1] | HLB = |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }} Ammonium perfluorononanoate (APFN) is an anionic surfactant that in water forms liquid crystalline phases (Lyotropic liquid crystal). It is the ammonium salt of perfluorononanoic acid. The phase diagram of APFN/H2O system is delineated by the presence of a lamellar phase and a nematic phase with awide isotropic solution. The nematic phase is of the type I, and the aggregates have a positive and diamagnetic anisotropy. In the presence of a magnetic field, the aggregates align parallel to the field direction. The change of phase at the lamellar-nematic temperature has been ascribed to order-disorder transitions. MLV FormationIt has recently been shown that the lamellar phase of the APFN/2H2O system form multilamellar vesicles under shear rate.[2] References1. ^{{cite journal|last1=Ivanchev|first1=S. S.|last2=Likhomanov|first2=V. S.|last3=Primachenko|first3=O. N.|last4=Khaikin|first4=S. Ya.|last5=Barabanov|first5=V. G.|last6=Kornilov|first6=V. V.|last7=Odinokov|first7=A. S.|last8=Kulvelis|first8=Yu. V.|last9=Lebedev|first9=V. T.|last10=Trunov|first10=V. A.|title=Scientific principles of a new process for manufacturing perfluorinated polymer electrolytes for fuel cells|journal=Petroleum Chemistry|volume=52|issue=7|year=2012|pages=453–461|issn=0965-5441|doi=10.1134/S0965544112070067}} 2. ^{{cite journal | doi = 10.1021/la102887e | title = Evidence of Formation of Ammonium Perfluorononanoate/2H2O Multilamellar Vesicles: Morphological Analysis by Rheology and Rheo-2H NMR Experiments | year = 2010 | last1 = Coppola | first1 = Luigi | last2 = Gentile | first2 = Luigi | last3 = Nicotera | first3 = Isabella | last4 = Rossi | first4 = Cesare Oliviero | last5 = Ranieri | first5 = Giuseppe Antonio | journal = Langmuir | volume = 26 | issue = 24 | pages = 19060–5 | pmid = 21073179}} 5 : Colloidal chemistry|Soft matter|Ammonium compounds|Perfluorinated compounds|Anionic surfactants |
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