“Bis(pyridine)iodonium(I) tetrafluoroborate”的意思、由来-开放百科全书

词条

Bis(pyridine)iodonium(I) tetrafluoroborate

释义

References

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| ImageFile = Bis(pyridine)iodonium(I) tetrafluoroborate.png
| ImageFile1 =Bis(pyridine)iodonium(I) tetrafluoroborate from crystal.png
| ImageSize =
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| IUPACName =
| OtherNames =Barluenga's Reagent
|Section1={{Chembox Identifiers
| CASNo = 15656-28-7
| PubChem = 10883201
| PubChem_Comment = erroneous content
| ChemSpiderID = 2016454
| StdInChI=1S/C10H10IN2.BF4/c1-3-7-12(8-4-1)11-13-9-5-2-6-10-13;2-1(3,4)5/h1-10H;/q+1;-1
| StdInChIKey = BMDSRCBKJZCUBH-UHFFFAOYSA-N
| SMILES = [B-](F)(F)(F)F.C1=CC=CC=N1[I+]N2C=CC=CC=2 }}
|Section2={{Chembox Properties
| C=10 | H=10 | B=1 | F=4 | I=1 | N=2
| MolarMass =
| Appearance =
| Density =
| MeltingPt =
| BoilingPt =
| Solubility = }}
|Section3={{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt =
| GHSPictograms = {{GHS07}}
| GHSSignalWord = Warning
| HPhrases = {{H-phrases|315|319|335}}
| PPhrases = {{P-phrases|261|264|271|280|302+352|304+340|305+351+338|312|321|332+313|337+313|362|403+233|405|501}}
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}}Bis(pyridine)iodonium(I) tetrafluoroborate or Barluenga's reagent named after José Barluenga,^[1] is a mild iodinating reagent. Commercially available, it may be prepared by reacting iodine with pyridine in the presence of silver tetrafluoroborate supported on silica gel.^[2]

References

1. ^{{cite journal | last1 = Martín | first1 = Nazario | last2 = Muñiz | first2 = Kilian | title = Congratulations to Professor José Barluenga on his 70th Birthday | journal = Chemistry: A European Journal | volume = 16 | issue = 32 | pages = 9696–9697 | year = 2010 | doi = 10.1002/chem.201001986 }}
2. ^{{OrgSynth | prep = v87p0288 | title = Safe and Scalable Preparation of Barluenga's Reagent | author = Justin M. Chalker | author2 = Amber L. Thompson | author3 = Benjamin G. Davis | last-author-amp = yes | volume = 87 | pages = 288 | year = 2010}}

3 : Tetrafluoroborates|Iodine compounds|Reagents for organic chemistry

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