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词条 Born–Mayer equation
释义

  1. See also

  2. References

The Born–Mayer equation is an equation that is used to calculate the lattice energy of a crystalline ionic compound. It is a refinement of the Born–Landé equation by using an improved repulsion term.[1]

where:

  • NA = Avogadro constant;
  • M = Madelung constant, relating to the geometry of the crystal;
  • z+ = charge number of cation
  • z = charge number of anion
  • e = elementary charge, 1.6022{{e|−19}} C
  • ε0 = permittivity of free space

4{{pi}}ε0 = 1.112{{e|−10}} C2/(J·m)

  • r0 = distance to closest ion
  • ρ = a constant dependant on the compressibility of the crystal; 30 pm works well for all alkali metal halides

See also

  • Born–Landé equation
  • Kapustinskii equation

References

1. ^{{cite web|url=http://alpha.chem.umb.edu/chemistry/ch370/CH370_Lectures/Lecture%20Documents/Ch07_2_LatticeEnergy.pdf|title=Lattice Energy}}
{{DEFAULTSORT:Born-Mayer Equation}}

2 : Solid-state chemistry|Ions

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