| 词条 | Cerium(III) methanesulfonate |
| 释义 |
| ImageFile = Cerium(III) methanesulfonate.svg | ImageSize = 200px | ImageAlt = | IUPACName = | OtherNames = {{ubl|Cerous methanesulfonate|Cerium(III) mesylate}} |Section1={{Chembox Identifiers | CASNo = 73640-09-2 | PubChem = 11826045 | ChemSpiderID = 10000696 | SMILES = CS(=O)(=O)[O-].CS(=O)(=O)[O-].CS(=O)(=O)[O-].[Ce+3] | InChI = 1/3CH4O3S.Ce/c3*1-5(2,3)4;/h3*1H3,(H,2,3,4);/q;;;+3/p-3 | InChIKey = XPQVQIJYDXCEKC-DFZHHIFOAL | StdInChI = 1S/3CH4O3S.Ce/c3*1-5(2,3)4;/h3*1H3,(H,2,3,4);/q;;;+3/p-3 | StdInChIKey = XPQVQIJYDXCEKC-UHFFFAOYSA-K | CASNo1 = 77998-20-0 | CASNo1_Comment = (dihydrate) }} |Section2={{Chembox Properties | Formula = Ce(CH3SO3)3 | MolarMass = 461.46 g/mol | Appearance = White crystalline solid[1] | Density = | MeltingPt = | BoilingPt = | Solubility = }} |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }} }} Cerium(III) methanesulfonate is a white salt, usually found as the dihydrate with the formula Ce(CH3SO3)3·2H2O that precipitates from the neutralisation of cerium(III) carbonate with methanesulfonic acid, as first reported by L.B. Zinner in 1979.[2][3] The crystals have a monoclinic polymeric structure were each methanesulfonate ion forms bonds with two cerium atoms, which present a coordination number of 8.[4] The anhydrous salt is formed by water loss at 120 °C. Similar methanesulfonates can be prepared with other lanthanides.[5] Cerium(III) methanesulfonate in solution is used as a precursor of electrogenerated cerium(IV), which is a strong oxidant and whose salts can be used in organic synthesis.[6] The same principle of Ce(IV) electrogeneration is the fundamental reaction in the positive half-cell of the zinc–cerium battery. See also
References1. ^{{cite journal|doi=10.1002/047084289X.rc044 | title=Cerium (III) Methanesulfonate | year=2001 | journal=Encyclopedia of Reagents for Organic Synthesis | last1 = Kreh | first1 = Robert P.}} {{Cerium compounds}}2. ^{{cite journal|last1=Zinner|first1=L.B.|title=Hydrated lanthanide methanesulfonates|journal=Academia Brasileira de Ciências|date=1979|volume=30|page=27}} 3. ^{{cite journal|last1=Zinner|first1=L.B.|title=Anhydrous lanthanide (III) methanesulfonates|journal=Academia Brasileira de Ciências|date=1980|volume=52|issue=4|page=715}} 4. ^{{cite journal|last1=Aricó|first1=E.M|last2=Zinner|first2=L.B.|last3=Apostolidis|first3=C.|last4=Dornberger|first4=E.|last5=Kanellakopulos|first5=B.|last6=Rebizant|first6=J.|title=Structures of the anhydrous Yb(III) and the hydrated Ce(III), Sm(III) and Tb(III) methanesulfonates|journal=Journal of Alloys and Compounds|date=1997|volume=249|pages=111–115|doi=10.1016/s0925-8388(96)02756-9 }} 5. ^{{cite journal|last1=Aricó|first1=E.M.|last2=Zinner|first2=L.B.|last3=Kanellakopulos|first3=B.|last4=Dornberger|first4=E.|last5=Rebizante|first5=J.|last6=Apostolidis|first6=C.|title=Structure and properties of hydrated La(III), Nd(III) and Er(III) methanesulfonates|journal=Journal of Alloys and Compounds|date=2001|volume=323–324|pages=39–44|doi=10.1016/s0925-8388(01)00975-6 }} 6. ^{{cite journal|last1=Kreh|first1=Robert P.|title=Mediated electrochemical synthesis of aromatic aldehydes, ketones, and quinones using ceric methanesulfonate|journal=The Journal of Organic Chemistry|date=1989|volume=54|issue=7|pages=1526–1531|doi=10.1021/jo00268a010}} 3 : Cerium(III) compounds|Oxidizing agents|Sulfonates |
| 随便看 |
|
开放百科全书收录14589846条英语、德语、日语等多语种百科知识，基本涵盖了大多数领域的百科知识，是一部内容自由、开放的电子版国际百科全书。