“Cinnamoyl-CoA”的意思、由来-开放百科全书

词条

Cinnamoyl-CoA

释义

Enzymes using Cinnamoyl-Coenzyme A
References

{{chembox
| Watchedfields =
| verifiedrevid =
| Name = Cinnamoyl-Coenzyme A
| ImageFile = Cinnamoyl-CoA.svg
| ImageSize = 250px
| IUPACName = S-[2-[3-[[(2R)-4-[[[(2R,3S,4R,5R)-5-(6-aminopurin-9-yl)-4-hydroxy-3-phosphonooxyoxolan-2-yl]methoxy-hydroxyphosphoryl]oxy-hydroxyphosphoryl]oxy-2-hydroxy-3,3-dimethylbutanoyl]amino]propanoylamino]ethyl](E)-3-phenylprop-2-enethioate
| OtherNames = Cinnamoyl-coa
(E)-cinnamoyl-CoA
Coenzyme A, S-(3-phenyl-2-propenoate)
(E)-benzylideneacetyl-CoA
3-phenylacryloyl-CoA
|Section1={{Chembox Identifiers
| CASNo_Ref =
| CASNo = 76109-04-1
| PubChem = 6444037
| ChemSpiderID = 4947984
| SMILES = CC(C)(COP(=O)(O)OP(=O)(O)OC[C@@H]1[C@H]([C@H]([C@@H](O1)N2C=NC3=C(N=CN=C32)N)O)OP(=O)(O)O)[C@H](C(=O)NCCC(=O)NCCSC(=O)/C=C/C4=CC=CC=C4)O
| InChI = 1/C30H42N7O17P3S/c1-30(2,25(41)28(42)33-11-10-20(38)32-12-13-58-21(39)9-8-18-6-4-3-5-7-18)15-51-57(48,49)54-56(46,47)50-14-19-24(53-55(43,44)45)23(40)29(52-19)37-17-36-22-26(31)34-16-35-27(22)37/h3-9,16-17,19,23-25,29,40-41H,10-15H2,1-2H3,(H,32,38)(H,33,42)(H,46,47)(H,48,49)(H2,31,34,35)(H2,43,44,45)/b9-8+/t19-,23-,24-,25+,29-/m1/s1
| InChIKey = JVNVHNHITFVWIX-KZKUDURGBU
| StdInChI = 1S/C30H42N7O17P3S/c1-30(2,25(41)28(42)33-11-10-20(38)32-12-13-58-21(39)9-8-18-6-4-3-5-7-18)15-51-57(48,49)54-56(46,47)50-14-19-24(53-55(43,44)45)23(40)29(52-19)37-17-36-22-26(31)34-16-35-27(22)37/h3-9,16-17,19,23-25,29,40-41H,10-15H2,1-2H3,(H,32,38)(H,33,42)(H,46,47)(H,48,49)(H2,31,34,35)(H2,43,44,45)/b9-8+/t19-,23-,24-,25+,29-/m1/s1
| StdInChIKey = JVNVHNHITFVWIX-KZKUDURGSA-N
| MeSHName =
|Section2={{Chembox Properties
| Formula = C₃₀H₄₂N₇O₁₇P₃S
| MolarMass = 897.68 g/mol
| Appearance =
| Density =
| MeltingPt =
| BoilingPt =
|Section3={{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt =
}}

Cinnamoyl-Coenzyme A is an intermediate in the phenylpropanoids metabolic pathway.

Enzymes using Cinnamoyl-Coenzyme A

Cinnamoyl-CoA reductase, an enzyme that catalyzes the chemical reaction cinnamaldehyde + CoA + NADP+ → cinnamoyl-CoA + NADPH + H+
Pinosylvin synthase, an enzyme that catalyzes the chemical reaction 3 malonyl-CoA + cinnamoyl-CoA → 4 CoA + pinosylvin + 4 CO₂
phenyllactate CoA-transferase, an enzyme that catalyzes the chemical reaction (E)-cinnamoyl-CoA + (R)-phenyllactate → (E)-cinnamate + (R)-phenyllactyl-CoA

References

2 : Thioesters of coenzyme A|Hydroxycinnamic acid esters

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