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词条 Diphosphene
释义

  1. References

{{Chembox
| Watchedfields = changed
| verifiedrevid = 451633982
| ImageFile = Diphosphene.png
| ImageSize = 150px
| ImageFile_Ref = {{Chemboximage|correct|??}}
| ImageName = Ball and stick model of diphosphene molecule
|Section1={{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 41916-72-7
| PubChem = 142559
| ChemSpiderID = 125761
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| SMILES = P=P
| StdInChI = 1S/H2P2/c1-2/h1-2H
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = SWJAOBXRZSMKNS-UHFFFAOYSA-N
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
|Section2={{Chembox Properties
| Formula = {{Chem|P|2|H|2}}
| MolarMass = 63.96340 g·mol−1
|Section9={{Chembox Related
| OtherCations = diphosphenes
| OtherAnions = diazene
| OtherFunction_label = Binary azenes
| OtherFunction = triazene
tetrazene
| OtherCompounds = ammonia
diazane
triazane
}}Diphosphene is a compound having the formula (PH)2. It exists as two geometric isomers, E and Z.[1] Diphosphene is also the parent member of the entire class of diphosphene compounds with the formula (PR)2, where R is an organyl group.[2]

References

1. ^{{cite journal | last = Lu | first = T. |author2=Simmonett, A. C. |author3=Evangelista, F. A. |author4=Yamaguchi, Y. |author5=Schaefer, H. F.| title = Diphosphene and Diphosphinylidene | journal = The Journal of Physical Chemistry A | year = 2009 | volume = 113 | issue = 47 | pages = 13227–13236 | doi = 10.1021/jp904028a }}
2. ^{{ cite journal | last = Yoshifuji | first=M. |author2=Shibayama, K. |author3=Inamoto, N. |author4=Hirotsu, K. |author5=Higuchi, T. | title = Reaction of the diphosphene ArP=PAr (Ar = 2,4,6-But3C6H2) with sulphur: isolation and X-ray structure of the diphosphene monosulphide | journal = Journal of the Chemical Society, Chemical Communications | year = 1983 | volume = 1983 | issue = 16 | pages = 862–863 | doi = 10.1039/C39830000862 }}
{{Hydrides by group}}{{Inorganic-compound-stub}}

1 : Phosphorus hydrides

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