词条 | Disulfur dibromide |
释义 | {{Chembox | Watchedfields = changed | verifiedrevid = 408467094 | Name = Sulfur dibromide | ImageFileL1 = Disulfur-dibromide-2D-dimensions.png | ImageNameL1 = Ball-and-stick model of sulfur dibromide | ImageFileR1 = Disulfur-dibromide-3D-balls.png | ImageNameR1 = Disulfur-dibromide-3D-vdW.png | IUPACName = bromosulfanyl thiohypobromite | OtherNames = Sulphur dibromide Sulfur(II) bromide Dibromosulfane Bromosulfanyl thiohypobromite |Section1={{Chembox Identifiers | SMILES = S(SBr)Br | CASNo = 13172-31-1 | PubChem = 123296 | CASNo_Ref = {{cascite|correct|CAS}} | RTECS = | EINECS = 236-119-1 | UNNumber = |Section2={{Chembox Properties | Formula = Br2S2 | MolarMass = 223.940 g mol−1 | Appearance = orange/yellow liquid | Density = 2.703 | Solubility = | MeltingPtC = | BoilingPtC = 54 | BoilingPt_notes = | RefractIndex = |Section3={{Chembox Structure | Coordination = C2, gauche | MolShape = | Dipole = |Section7={{Chembox Hazards | ExternalSDS = ICSC 1661 | EUClass = Corrosive (C) Irritant (Xi) Dangerous for the environment (N) | RPhrases = {{R14}}, {{R34}}, {{R37}}, {{R50}} | SPhrases = {{S1/2}}, {{S26}}, {{S45}}, {{S61}} | NFPA-H = | NFPA-F = | NFPA-R = | NFPA-S = | AutoignitionPt = | PEL = |Section8={{Chembox Related | OtherFunction = Sulfur dibromide Thionyl bromide Sulfuryl bromide | OtherCompounds = Disulfur difluoride Disulfur dichloride }} Disulfur dibromide is the chemical compound whose molecule is composed of two atoms each of sulfur and bromine. The molecular structure is akin to that of hydrogen peroxide (H2O2). Disulfur dibromide is the most stable sulfur bromide, however, its thermal stability is low. It is a toxic, orange/yellow liquid that smokes in air due to the reaction with water vapor. In the presence of moisture, disulfur dibromide reacts violently with oxidants, releasing bromide anion and sulfur oxides. In general, its reactivity resembles that of S2Cl2. {{Sulfur compounds}} 2 : Sulfur halides|Bromides |
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