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词条 Gold monoiodide
释义

  1. References

{{Chembox
| ImageFile1 = AuI structure.png
| ImageSize1 = 280 px
| IUPACName = Iodogold
| SystematicName= Gold(1+) iodide
| OtherNames = Gold monoiodide
|Section1={{Chembox Identifiers
| CASNo = 10294-31-2
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = T1UDV7ES1A
| PubChem = 82526
| ChemSpiderID = 74478
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| SMILES = [Au]I
| StdInChI = 1S/Au.HI/h;1H/q+1;/p-1
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = ATGIETUGWDAYPU-UHFFFAOYSA-M
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
|Section2={{Chembox Properties
| Formula = AuI
| MolarMass = 323.871 g/mol
| Appearance = Yellowish to greenish-yellow powder
| Density = 8.25 g/cm3[1]
| MagSus = −91.0·10−6 cm3/mol
|Section3={{Chembox Structure
| CrystalStruct = tetragonal, Pearson symbol tP8, Z = 4
| SpaceGroup = P42/ncm (No. 138)[1]
| Coordination =
| LattConst_a = 0.435
| LattConst_b = 0.435
| LattConst_c = 1.373 nm
| LattConst_alpha =
| LattConst_beta =
| LattConst_gamma =
| MolShape =
| OrbitalHybridisation =
| Dipole =
|Section7={{Chembox Hazards
| EUClass = {{hazchem Xi}}
| RPhrases = {{R36/37/38}}
| SPhrases = {{S26}}, {{S37/39}}
}}Gold monoiodide (AuI) is a chemical compound of gold and iodine. This compound is commercially available. It can be synthesized by heating gold and iodine in a sealed tube at 120°C for about four months. It decomposes when treated with hot water.[2] But its related complexes are much more stable.[3]

References

1. ^{{cite journal|author=Jagodzinski H. |journal=Z. Kristallogr.|year=1959|volume=112|title= Die Kristallstruktur des AuJ|pages=80–87}}
2. ^{{Greenwood&Earnshaw2nd}}
3. ^{{cite journal|last=Tang|first=Zhongjia|author2=Litvinchuk, A. P. |author3=Lee, Hye-G. |author4= Guloy, Arnold M. |title=Crystal Structure and Vibrational Spectra of a New Viologen Gold(I) Iodide|journal=Inorganic Chemistry|date=1 September 1998|volume=37|issue=19|pages=4752–4753|doi=10.1021/ic980141q}}
{{inorganic-compound-stub}}{{Gold compounds}}

4 : Gold(Ⅰ) compounds|Iodides|Metal halides|Gold-halogen compounds

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