词条 | Gold monoiodide |
释义 |
| ImageFile1 = AuI structure.png | ImageSize1 = 280 px | IUPACName = Iodogold | SystematicName= Gold(1+) iodide | OtherNames = Gold monoiodide |Section1={{Chembox Identifiers | CASNo = 10294-31-2 | UNII_Ref = {{fdacite|correct|FDA}} | UNII = T1UDV7ES1A | PubChem = 82526 | ChemSpiderID = 74478 | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | SMILES = [Au]I | StdInChI = 1S/Au.HI/h;1H/q+1;/p-1 | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = ATGIETUGWDAYPU-UHFFFAOYSA-M | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} |Section2={{Chembox Properties | Formula = AuI | MolarMass = 323.871 g/mol | Appearance = Yellowish to greenish-yellow powder | Density = 8.25 g/cm3[1] | MagSus = −91.0·10−6 cm3/mol |Section3={{Chembox Structure | CrystalStruct = tetragonal, Pearson symbol tP8, Z = 4 | SpaceGroup = P42/ncm (No. 138)[1] | Coordination = | LattConst_a = 0.435 | LattConst_b = 0.435 | LattConst_c = 1.373 nm | LattConst_alpha = | LattConst_beta = | LattConst_gamma = | MolShape = | OrbitalHybridisation = | Dipole = |Section7={{Chembox Hazards | EUClass = {{hazchem Xi}} | RPhrases = {{R36/37/38}} | SPhrases = {{S26}}, {{S37/39}} }}Gold monoiodide (AuI) is a chemical compound of gold and iodine. This compound is commercially available. It can be synthesized by heating gold and iodine in a sealed tube at 120°C for about four months. It decomposes when treated with hot water.[2] But its related complexes are much more stable.[3] References1. ^1 {{cite journal|author=Jagodzinski H. |journal=Z. Kristallogr.|year=1959|volume=112|title= Die Kristallstruktur des AuJ|pages=80–87}} {{inorganic-compound-stub}}{{Gold compounds}}2. ^{{Greenwood&Earnshaw2nd}} 3. ^{{cite journal|last=Tang|first=Zhongjia|author2=Litvinchuk, A. P. |author3=Lee, Hye-G. |author4= Guloy, Arnold M. |title=Crystal Structure and Vibrational Spectra of a New Viologen Gold(I) Iodide|journal=Inorganic Chemistry|date=1 September 1998|volume=37|issue=19|pages=4752–4753|doi=10.1021/ic980141q}} 4 : Gold(Ⅰ) compounds|Iodides|Metal halides|Gold-halogen compounds |
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