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词条 Hafnium tetrafluoride
释义

  1. References

  2. Further reading

{{chembox
| verifiedrevid = 470637858
| Name = Hafnium(IV) fluoride
| ImageFile =Kristallstruktur Uran(IV)-fluorid.png
| ImageName = Zirconium(IV) fluoride
| IUPACName = Hafnium(IV) fluoride
Hafnium tetrafluoride
| OtherNames =
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 3306631
| PubChem = 50925283
| CASNo = 13709-52-9
| CASNo_Ref = {{cascite|correct|CAS}}
| EINECS = 237-258-0
| StdInChI=1S/4FH.Hf/h4*1H;/q;;;;+4/p-4
| StdInChIKey = QHEDSQMUHIMDOL-UHFFFAOYSA-J
| SMILES = [F-].[F-].[F-].[F-].[Hf+4]
|Section2={{Chembox Properties
| Formula = HfF4
| MolarMass =
| Appearance = white crystalline powder
| Density = 7.1 g/cm3[1]
| Solubility =
| MeltingPt =
| BoilingPtC = 970
| BoilingPt_notes = (sublimes)[1]
|Section3={{Chembox Structure
| CrystalStruct = Monoclinic, mS60[2]
| SpaceGroup = C2/c, No. 15
| LattConst_a = 1.17 nm
| LattConst_b= 0.986 nm
| LattConst_c=0.764 nm
|Section7={{Chembox Hazards
| ExternalSDS =
| NFPA-H =
| NFPA-R =
| NFPA-F =
| NFPA-S =
| FlashPt = Non-flammable
| LD50 =
|Section8={{Chembox Related
| OtherAnions = Hafnium(IV) chloride
| OtherCations = Titanium(IV) fluoride
}}

Hafnium tetrafluoride is the inorganic compound with the formula HfF4. It is a white solid. It adopts the same structure as zirconium tetrafluoride, with 8-coordinate Hf(IV) centers.

References

1. ^{{RubberBible92nd|page=4.66}}
2. ^{{Cite journal | doi = 10.1107/S0365110X49001016| title = Crystal chemical studies of the 5f-series of elements. XII. New compounds representing known structure types| journal = Acta Crystallographica| volume = 2| issue = 6| pages = 388| year = 1949| last1 = Zachariasen | first1 = W. H.}}

Further reading

  • Benjamin, S. L., Levason, W., Pugh, D., Reid, G., Zhang, W., "Preparation and structures of coordination complexes of the very hard Lewis acids ZrF4 and HfF4", Dalton Transactions 2012, 41, 12548. {{DOI|10.1039/C2DT31501G}}
{{Hafnium compounds}}{{Fluorine compounds}}{{Inorganic-compound-stub}}

3 : Hafnium compounds|Fluorides|Metal halides

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