“Homolycorine”的意思、由来-开放百科全书

词条

Homolycorine

释义

Sources

{{chembox
| Verifiedfields = changed
| verifiedrevid =
| ImageFile=Homolycorine.svg
| ImageSize=200px
| IUPACName= (5aR,11bS,11cS)-9,10-Dimethoxy-1-methyl-2,3,5,5a,11b,11c-hexahydroisochromeno[3,4-g]indol-7-one
| OtherNames= 9,10-Dimethoxy-1-methyllycorenan-7-one
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 141017
| InChI =
| InChIKey =
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = InChI=1S/C18H21NO4/c1-19-7-6-10-4-5-13-16(17(10)19)11-8-14(21-2)15(22-3)9-12(11)18(20)23-13/h4,8-9,13,16-17H,5-7H2,1-3H3/t13-,16-,17-/m1/s1
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = WXZAKVLYZHWSNF-KBRIMQKVSA-N
| CASNo_Ref = {{cascite|changed|??}}
| CASNo= 477-20-3
| ChEMBL_Ref = {{ebicite|correct|EBI}}
| ChEMBL = 1221973
| PubChem=160473
| ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEBI =
| SMILES = COc1cc2[C@@H]3[C@@H](CC=C4CCN(C)[C@@H]34)OC(=O)c2cc1OC}}
|Section2={{Chembox Properties
| C=18 | H=21 | N=1 | O=4
| Appearance=
| Density=
| MeltingPt=
| BoilingPt=
| Solubility=
|Section3={{Chembox Hazards
| MainHazards=
| FlashPt=
| AutoignitionPt =
}}

Homolycorine is one of a number of toxic alkaloids found in various Amaryllidaceae species such as daffodils (Narcissus).

Sources

Four new Amaryllidaceae alkaloids from Zephyranthes candida. Shitara N, Hirasawa Y, Hasumi S, Sasaki T, Matsumoto M, Wong CP, Kaneda T, Asakawa Y, Morita H (2014 Jul) Journal of natural medicines, 68(3):610-4
Acta Crystallographica
T. Kitagawa, W. I. Taylor, S. Uyeo and H. Yajima. The constitution of homolycorine and lycorenine J. Chem. Soc., 1955, 1066-1068 DOI: 10.1039/JR9550001066
[https://www.researchgate.net/publication/6664419_Chemical_and_biological_aspects_of_Narcissus_alkaloids/file/79e415020c218c82b0.pdf Bastida, Jaume, Rodolfo Lavilla, and Francesc Viladomat. "CHEMICAL AND BIOLOGICAL ASPECTS OF Narcissus ALKALOIDS", in “The Alkaloids: Chemistry and Biology” (G. A. Cordell, ed.), Vol. 63 pp. 87-179 (2006). Elsevier Inc. Amsterdam. DOI: 10.1016/S1099-4831(06)63003-4]

3 : Lactones|Alkaloids|Dihydroisocoumarins

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