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词条 Lithium methoxide
释义

  1. See also

  2. References

{{Chembox
| ImageFile =   
| ImageSize =
| IUPACName = Lithium methanolate
| OtherNames =
|Section1={{Chembox Identifiers
| CASNo = 865-34-9
| PubChem = 164741
| ChemSpiderID = 144418
| SMILES = [Li+].[O-]C
| InChI = 1/CH3O.Li/c1-2;/h1H3;/q-1;+1
| InChIKey = JILPJDVXYVTZDQ-UHFFFAOYAW
| StdInChI = 1S/CH3O.Li/c1-2;/h1H3;/q-1;+1
| StdInChIKey = JILPJDVXYVTZDQ-UHFFFAOYSA-N
|Section2={{Chembox Properties
| Formula = CH3LiO
| MolarMass = 37.975
| Appearance =
| Density =
| MeltingPt =
| BoilingPt =
| Solubility =
|Section3={{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt =
}}Lithium methoxide is a compound with formula LiCH3O. It is the lithium salt of methanol. Unlike the lithium alkoxides derived from the heavier alcohols, lithium methoxide is largely ionic in its bonding.[1] Its solubility in common polar aprotic solvents like THF is low; however, it is soluble in methanol and is available commercially as a 10% solution.[2]

See also

  • Methoxide

References

1. ^{{Cite journal|last=WHEATLEY|first=P. J.|date=1960-03-05|title=Structure of Lithium Methoxide|url=https://www.nature.com/nature/journal/v185/n4714/abs/185681b0.html|journal=Nature|language=en|volume=185|issue=4714|pages=681–682|doi=10.1038/185681b0}}
2. ^{{Cite web|url=http://www.fmclithium.com/Portals/FMCLithium/content/docs/DataSheet/QS-PDS-014%20r2.pdf|title=Lithium Methoxide (LiOMe) in 10% Methanol|date=2016|website=FMC lithium|access-date=6 Sep 2017}}
{{inorganic-compound-stub}}

2 : Lithium compounds|Alkoxides

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